On/off regulation of catalysis by allosteric control of metal complex nuclearity

The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)]2+ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.

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Published in:Chemical communications (Cambridge, England) England), 2004-04 (7), p.880-881
Main Authors: Kovbasyuk, Larisa, Pritzkow, Hans, Krämer, Roland, Fritsky, Igor O
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Language:English
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description The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)]2+ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.
doi_str_mv 10.1039/b316225g
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title On/off regulation of catalysis by allosteric control of metal complex nuclearity
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