catena-Poly[[[bis(μ-4,5-dihydrothiazole-2-thiolato)-tetrahedro-tetracopper(I)]-di-μ-4,5-dihydrothiazole-2-thiolato] dihydrate]

The title compound, {[Cu4(C3H4NS2)4]·2H2O}n, was produced by diffusing a solution of 2‐mercapto­thia­zoline in tetra­hydro­furan into a solution of CuCl in CH3CN at room temperature. The structure is characterized by self‐assembled one‐dimensional chains that are condensed from butterfly‐like [Cu(C3...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2002-07, Vol.58 (7), p.m396-m397
Main Authors: Du, Ji-Min, Zeng, Hui-Yi, Dong, Zhen-Chao, Guo, Guo-Cong, Huang, Jin-Shun
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:The title compound, {[Cu4(C3H4NS2)4]·2H2O}n, was produced by diffusing a solution of 2‐mercapto­thia­zoline in tetra­hydro­furan into a solution of CuCl in CH3CN at room temperature. The structure is characterized by self‐assembled one‐dimensional chains that are condensed from butterfly‐like [Cu(C3H4NS2)]4 tetrameric units via double S‐bridging at opposite ends. The Cu—Cu distances within the Cu4 butterfly cluster are in the range 2.7103 (10)–2.9764 (10) Å, while the shortest Cu⋯Cu intercluster distance is 3.468 (1) Å, much longer than the sum of the van der Waals radii.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270102009198