Synthesis of Amines from Imines in the Coordination Sphere of Silicon-Surprising Photo-Rearrangement of Hexacoordinate Organosilanes
There's room at the top: In the coordination sphere of hexacoordinate organosilanes with O‐ and N‐donor ligands (see picture) the SiC bond is elongated and activated. This effect is so strongly pronounced that cleavage of one SiC bond and migration of this organo substituent takes place upon...
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Published in: | Angewandte Chemie International Edition 2004-04, Vol.43 (18), p.2441-2444 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | There's room at the top: In the coordination sphere of hexacoordinate organosilanes with O‐ and N‐donor ligands (see picture) the SiC bond is elongated and activated. This effect is so strongly pronounced that cleavage of one SiC bond and migration of this organo substituent takes place upon irradiation with UV light to give a pentacoordinate silicon complex. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200353267 |