Sex pheromone biosynthesis in the female olive fruit-fly. Double labelling from [18O2]-dioxygen into 1,7-dioxaspiro[5.5]undecane

The demonstration that both oxygen atoms of 1,7-dioxaspiro[5.5]undecane (1), the sex-pheromone of the female olive fly, originate from dioxygen, strongly implicates monooxygenase mediated processes in assembly of (1), and reveals unexpected complexity in the formation of its nine-carbon precursor.

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Published in:Chemical communications (Cambridge, England) England), 2002-06 (12), p.1302-1303
Main Authors: Fletcher, Mary T, Mazomenos, Basilis E, Georgakopoulos, John H, Konstantopoulou, Maria A, Wood, Barry J, De Voss, James J, Kitching, William
Format: Article
Language:English
Subjects:
Animals
Drosophila - metabolism
Female
Isotope Labeling
Oxygen - metabolism
Oxygen Isotopes
Sex Attractants - biosynthesis
Spiro Compounds - metabolism
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cited_by cdi_FETCH-LOGICAL-c299t-f11c207a11f55b8cf3ec536e37aa35ca11c9da2c2b2d45f7e4597e1df94aeffa3
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container_issue 12
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container_title Chemical communications (Cambridge, England)
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creator Fletcher, Mary T
Mazomenos, Basilis E
Georgakopoulos, John H
Konstantopoulou, Maria A
Wood, Barry J
De Voss, James J
Kitching, William
description The demonstration that both oxygen atoms of 1,7-dioxaspiro[5.5]undecane (1), the sex-pheromone of the female olive fly, originate from dioxygen, strongly implicates monooxygenase mediated processes in assembly of (1), and reveals unexpected complexity in the formation of its nine-carbon precursor.
doi_str_mv 10.1039/b202697j
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source Royal Society of Chemistry: Jisc Collections: Journals Archive 1841-2007 (2019-2023)
subjects Animals
Drosophila - metabolism
Female
Isotope Labeling
Oxygen - metabolism
Oxygen Isotopes
Sex Attractants - biosynthesis
Spiro Compounds - metabolism
title Sex pheromone biosynthesis in the female olive fruit-fly. Double labelling from [18O2]-dioxygen into 1,7-dioxaspiro[5.5]undecane
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