Monoalkyl, chiral-at-metal 'constrained geometry' complexes as efficient alpha-olefin and methyl methacrylate polymerisation catalysts

A new class of monoalkyl or monochloro constrained geometry group 4 complexes has been synthesized; upon activation with aluminium activators they serve as efficient catalysts for olefin polymerisation and for polymerisation of methyl methacrylate.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2002-04 (7), p.708-709
Main Authors: Jin, Jizhu, Wilson, David R, Chen, Eugene Y X
Format: Article
Language:English
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Description
Summary:A new class of monoalkyl or monochloro constrained geometry group 4 complexes has been synthesized; upon activation with aluminium activators they serve as efficient catalysts for olefin polymerisation and for polymerisation of methyl methacrylate.
ISSN:1359-7345
1364-548X
DOI:10.1039/b201346k