Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand

The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C-H insertion into the ferrocene.

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2002-02 (4), p.308-309
Main Authors: Farrington, Edward J, Martinez Viviente, Eloisa, Williams, B Scott, van Koten, Gerard, Brown, John M
Format: Article
Language:English
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C-H insertion into the ferrocene.
ISSN:1359-7345
1364-548X
DOI:10.1039/b108585a