A three-dimensional zeolite-like organic-inorganic hybrid material constructed from (CuMo2O8N)n double helical chains linked via [Cu(4,4'-bpy)]n fragments

The three-dimensional microporous [Cu2Mo2O8(4,4'-bpy)]n.3nH2O 1 contains (CuMo2O8N) double helical chains, which are built up from (CuIIO4N) square pyramids linked by (MoVIO4) tetrahedra and further connected to each other by 4,4'-bpy coordinated (CuIIO5N); the study of the physical proper...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2002-01 (2), p.152-153
Main Authors: Lu, Can-Zhong, Wu, Chuan-De, Lu, Shao-Fang, Liu, Jia-Cheng, Wu, Qiang-Jin, Zhuang, Hong-Hui, Huang, Jin-Shun
Format: Article
Language:English
Online Access:Get full text
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Summary:The three-dimensional microporous [Cu2Mo2O8(4,4'-bpy)]n.3nH2O 1 contains (CuMo2O8N) double helical chains, which are built up from (CuIIO4N) square pyramids linked by (MoVIO4) tetrahedra and further connected to each other by 4,4'-bpy coordinated (CuIIO5N); the study of the physical properties of 1 demonstrates it is a paramagnetic semiconductor and a zeolite material; the specific channeling cavities in 1 have potential adsorption activities, indicating that 1 might be an attractive functional microporous solid material.
ISSN:1359-7345
DOI:10.1039/b108704e