Loading…
Iron(III) complexing ability of carbohydrate derivatives
A solution study on the coordinative ability of galactaric acid (GalAH 2), d-glucosamine (GlcN) and d-glucosaminic acid (GlcNAH) toward Fe 3+ ion is reported. UV spectroscopic study provides useful information to identify complex species formation and their stability constants are determined by mean...
Saved in:
| Published in: | Journal of inorganic biochemistry 2004-06, Vol.98 (6), p.1002-1008 |
|---|---|
| Main Authors: | , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3 |
| container_end_page | 1008 |
| container_issue | 6 |
| container_start_page | 1002 |
| container_title | Journal of inorganic biochemistry |
| container_volume | 98 |
| creator | Ferrari, E. Saladini, M. |
| description | A solution study on the coordinative ability of galactaric acid (GalAH
2),
d-glucosamine (GlcN) and
d-glucosaminic acid (GlcNAH) toward Fe
3+ ion is reported. UV spectroscopic study provides useful information to identify complex species formation and their stability constants are determined by means of potentiometric measurements. GalAH
2 behaves as chelating ligand through carboxylic oxygen and α-hydroxylic oxygen in the protonated or dissociated form depending on pH value. Two complex species [Fe
2GalA(OH)
4] and Na[FeGalAH
−2]
·
2H
2O are also isolated in the solid state and characterised through IR spectroscopy. GlcNAH also binds the Fe
3+ ion through carboxylic and hydroxylic groups, while NH
2 group is probably involved in metal coordiantion up to pH 4. GlcN demonstrates low ligating ability at acidic pH and does not prevent metal hydroxyde precipitation. |
| doi_str_mv | 10.1016/j.jinorgbio.2004.02.017 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_71950289</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0162013404000534</els_id><sourcerecordid>71950289</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3</originalsourceid><addsrcrecordid>eNqFkMtOwzAQRS0EgvL4BcgKwSJh_EjsLFHFI1IlNrC2YmcCjtK42GlF_56gVrBkNZtz79UcQq4oZBRocddlnRt8eDfOZwxAZMAyoPKAzKiSPOVciEMym0iWAuXihJzG2AFAngt5TE5oTkWpQM2IqoIfbqqquk2sX656_HLDe1Ib17txm_g2sXUw_mPbhHrEpMHgNvXoNhjPyVFb9xEv9veMvD0-vM6f08XLUzW_X6SWF3JMkYtccsYMaygHVMyo0ljByoKhKlpZyEKBBYUNlbVlfEo1jBeFEYBoWsPPyPWudxX85xrjqJcuWuz7ekC_jlrSMgemygmUO9AGH2PAVq-CW9ZhqynoH2m607_S9I80DUxP0qbk5X5ibZbY_OX2libgfgfg9OjGYdDROhwsNi6gHXXj3b8j35r6gR8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>71950289</pqid></control><display><type>article</type><title>Iron(III) complexing ability of carbohydrate derivatives</title><source>ScienceDirect Freedom Collection</source><creator>Ferrari, E. ; Saladini, M.</creator><creatorcontrib>Ferrari, E. ; Saladini, M.</creatorcontrib><description>A solution study on the coordinative ability of galactaric acid (GalAH
2),
d-glucosamine (GlcN) and
d-glucosaminic acid (GlcNAH) toward Fe
3+ ion is reported. UV spectroscopic study provides useful information to identify complex species formation and their stability constants are determined by means of potentiometric measurements. GalAH
2 behaves as chelating ligand through carboxylic oxygen and α-hydroxylic oxygen in the protonated or dissociated form depending on pH value. Two complex species [Fe
2GalA(OH)
4] and Na[FeGalAH
−2]
·
2H
2O are also isolated in the solid state and characterised through IR spectroscopy. GlcNAH also binds the Fe
3+ ion through carboxylic and hydroxylic groups, while NH
2 group is probably involved in metal coordiantion up to pH 4. GlcN demonstrates low ligating ability at acidic pH and does not prevent metal hydroxyde precipitation.</description><identifier>ISSN: 0162-0134</identifier><identifier>EISSN: 1873-3344</identifier><identifier>DOI: 10.1016/j.jinorgbio.2004.02.017</identifier><identifier>PMID: 15149808</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Carbohydrates - chemistry ; d-glucosamine ; d-glucosaminic acid ; Fe 3+ complexes ; Galactaric acid ; Hydrogen-Ion Concentration ; Iron - chemistry ; Iron Chelating Agents - chemistry ; Molecular Structure ; Organometallic Compounds - chemistry ; Potentiometric study ; Potentiometry</subject><ispartof>Journal of inorganic biochemistry, 2004-06, Vol.98 (6), p.1002-1008</ispartof><rights>2004 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3</citedby><cites>FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15149808$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ferrari, E.</creatorcontrib><creatorcontrib>Saladini, M.</creatorcontrib><title>Iron(III) complexing ability of carbohydrate derivatives</title><title>Journal of inorganic biochemistry</title><addtitle>J Inorg Biochem</addtitle><description>A solution study on the coordinative ability of galactaric acid (GalAH
2),
d-glucosamine (GlcN) and
d-glucosaminic acid (GlcNAH) toward Fe
3+ ion is reported. UV spectroscopic study provides useful information to identify complex species formation and their stability constants are determined by means of potentiometric measurements. GalAH
2 behaves as chelating ligand through carboxylic oxygen and α-hydroxylic oxygen in the protonated or dissociated form depending on pH value. Two complex species [Fe
2GalA(OH)
4] and Na[FeGalAH
−2]
·
2H
2O are also isolated in the solid state and characterised through IR spectroscopy. GlcNAH also binds the Fe
3+ ion through carboxylic and hydroxylic groups, while NH
2 group is probably involved in metal coordiantion up to pH 4. GlcN demonstrates low ligating ability at acidic pH and does not prevent metal hydroxyde precipitation.</description><subject>Carbohydrates - chemistry</subject><subject>d-glucosamine</subject><subject>d-glucosaminic acid</subject><subject>Fe 3+ complexes</subject><subject>Galactaric acid</subject><subject>Hydrogen-Ion Concentration</subject><subject>Iron - chemistry</subject><subject>Iron Chelating Agents - chemistry</subject><subject>Molecular Structure</subject><subject>Organometallic Compounds - chemistry</subject><subject>Potentiometric study</subject><subject>Potentiometry</subject><issn>0162-0134</issn><issn>1873-3344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EgvL4BcgKwSJh_EjsLFHFI1IlNrC2YmcCjtK42GlF_56gVrBkNZtz79UcQq4oZBRocddlnRt8eDfOZwxAZMAyoPKAzKiSPOVciEMym0iWAuXihJzG2AFAngt5TE5oTkWpQM2IqoIfbqqquk2sX656_HLDe1Ib17txm_g2sXUw_mPbhHrEpMHgNvXoNhjPyVFb9xEv9veMvD0-vM6f08XLUzW_X6SWF3JMkYtccsYMaygHVMyo0ljByoKhKlpZyEKBBYUNlbVlfEo1jBeFEYBoWsPPyPWudxX85xrjqJcuWuz7ekC_jlrSMgemygmUO9AGH2PAVq-CW9ZhqynoH2m607_S9I80DUxP0qbk5X5ibZbY_OX2libgfgfg9OjGYdDROhwsNi6gHXXj3b8j35r6gR8</recordid><startdate>20040601</startdate><enddate>20040601</enddate><creator>Ferrari, E.</creator><creator>Saladini, M.</creator><general>Elsevier Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20040601</creationdate><title>Iron(III) complexing ability of carbohydrate derivatives</title><author>Ferrari, E. ; Saladini, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Carbohydrates - chemistry</topic><topic>d-glucosamine</topic><topic>d-glucosaminic acid</topic><topic>Fe 3+ complexes</topic><topic>Galactaric acid</topic><topic>Hydrogen-Ion Concentration</topic><topic>Iron - chemistry</topic><topic>Iron Chelating Agents - chemistry</topic><topic>Molecular Structure</topic><topic>Organometallic Compounds - chemistry</topic><topic>Potentiometric study</topic><topic>Potentiometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ferrari, E.</creatorcontrib><creatorcontrib>Saladini, M.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of inorganic biochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ferrari, E.</au><au>Saladini, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Iron(III) complexing ability of carbohydrate derivatives</atitle><jtitle>Journal of inorganic biochemistry</jtitle><addtitle>J Inorg Biochem</addtitle><date>2004-06-01</date><risdate>2004</risdate><volume>98</volume><issue>6</issue><spage>1002</spage><epage>1008</epage><pages>1002-1008</pages><issn>0162-0134</issn><eissn>1873-3344</eissn><abstract>A solution study on the coordinative ability of galactaric acid (GalAH
2),
d-glucosamine (GlcN) and
d-glucosaminic acid (GlcNAH) toward Fe
3+ ion is reported. UV spectroscopic study provides useful information to identify complex species formation and their stability constants are determined by means of potentiometric measurements. GalAH
2 behaves as chelating ligand through carboxylic oxygen and α-hydroxylic oxygen in the protonated or dissociated form depending on pH value. Two complex species [Fe
2GalA(OH)
4] and Na[FeGalAH
−2]
·
2H
2O are also isolated in the solid state and characterised through IR spectroscopy. GlcNAH also binds the Fe
3+ ion through carboxylic and hydroxylic groups, while NH
2 group is probably involved in metal coordiantion up to pH 4. GlcN demonstrates low ligating ability at acidic pH and does not prevent metal hydroxyde precipitation.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>15149808</pmid><doi>10.1016/j.jinorgbio.2004.02.017</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0162-0134 |
| ispartof | Journal of inorganic biochemistry, 2004-06, Vol.98 (6), p.1002-1008 |
| issn | 0162-0134 1873-3344 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_71950289 |
| source | ScienceDirect Freedom Collection |
| subjects | Carbohydrates - chemistry d-glucosamine d-glucosaminic acid Fe 3+ complexes Galactaric acid Hydrogen-Ion Concentration Iron - chemistry Iron Chelating Agents - chemistry Molecular Structure Organometallic Compounds - chemistry Potentiometric study Potentiometry |
| title | Iron(III) complexing ability of carbohydrate derivatives |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T10%3A44%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Iron(III)%20complexing%20ability%20of%20carbohydrate%20derivatives&rft.jtitle=Journal%20of%20inorganic%20biochemistry&rft.au=Ferrari,%20E.&rft.date=2004-06-01&rft.volume=98&rft.issue=6&rft.spage=1002&rft.epage=1008&rft.pages=1002-1008&rft.issn=0162-0134&rft.eissn=1873-3344&rft_id=info:doi/10.1016/j.jinorgbio.2004.02.017&rft_dat=%3Cproquest_cross%3E71950289%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c367t-e3457322b2d130e82b89bc42962e86f767680c08ed17ac23c36d2366b40eebfb3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=71950289&rft_id=info:pmid/15149808&rfr_iscdi=true |