Synthesis of Multitopic Verdazyl Radical Ligands. Paramagnetic Supramolecular Synthons

The syntheses of several verdazyl radical and diradicals containing pyridine-based multitopic coordination sites are described. These compounds were designed to be paramagnetic analogues of oligopyridine metallosupramolecular building blocks.

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Bibliographic Details
Published in:Organic letters 2004-06, Vol.6 (12), p.1887-1890
Main Authors: Hicks, Robin G, Koivisto, Bryan D, Lemaire, Martin T
Format: Article
Language:English
Subjects:
Free Radicals - chemical synthesis
Free Radicals - chemistry
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
Ligands
Macromolecular Substances
Molecular Structure
Pyridines - chemistry
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Description
Summary:The syntheses of several verdazyl radical and diradicals containing pyridine-based multitopic coordination sites are described. These compounds were designed to be paramagnetic analogues of oligopyridine metallosupramolecular building blocks.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol049746i