New and Convenient Method for Incorporation of Pentafluorosulfanyl (SF5) Substituents Into Aliphatic Organic Compounds

Use of Et3B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF5Cl in high yield to a variety of alkenes and alkynes.

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Bibliographic Details
Published in:Organic letters 2002-08, Vol.4 (17), p.3013-3015
Main Authors: Aït-Mohand, Samia, Dolbier, William R
Format: Article
Language:English
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Description
Summary:Use of Et3B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF5Cl in high yield to a variety of alkenes and alkynes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol026483o