Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases:  Structural Characterization of Potassium, Calcium, and Mixed Potassium−Calcium Enolates

Potassium, calcium, and mixed potassium−calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2004-06, Vol.126 (24), p.7444-7445
Main Authors: He, Xuyang, Noll, Bruce C, Beatty, Alicia, Mulvey, Robert E, Henderson, Kenneth W
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Description
Summary:Potassium, calcium, and mixed potassium−calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja048750m