Parallels in Cation and Anion Coordination: A New Class of Cascade Complexes

Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion‐based cascade complex, which mimics the analogous transition‐metal cascade complexes with these ligands.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2002-07, Vol.41 (13), p.2335-2338
Main Authors: Hossain, Md. Alamgir, Llinares, José M., Mason, Susan, Morehouse, Paula, Powell, Douglas, Bowman-James, Kristin
Format: Article
Language:English
Subjects:
anions
bridging ligands
cascade complex
cryptands
macrocyclic ligands
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Online Access:Get full text
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Description
Summary:Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion‐based cascade complex, which mimics the analogous transition‐metal cascade complexes with these ligands.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20020703)41:13<2335::AID-ANIE2335>3.0.CO;2-3