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Structural studies on C-2 substitution in a new set of synthetic aminodideoxy sugars: the steric bulk at C-2 influences the puckering of the pyranose ring
Synthesis and single-crystal X-ray structural analyses of selected aminodideoxy sugars with different group substitutions at the C-2 position were carried out. Product formation and X-ray crystallographic determination of the products from C-2 substitution in both α and β anomers were studied. The o...
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| Published in: | Carbohydrate research 2002-09, Vol.337 (16), p.1507-1512 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c361t-f4431f9fcae18652021745d226263b6aa0aa3210ff1c03ee6416aff99ca001b83 |
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| cites | cdi_FETCH-LOGICAL-c361t-f4431f9fcae18652021745d226263b6aa0aa3210ff1c03ee6416aff99ca001b83 |
| container_end_page | 1512 |
| container_issue | 16 |
| container_start_page | 1507 |
| container_title | Carbohydrate research |
| container_volume | 337 |
| creator | Suresh, Chiravakkattu G. Ravindran, Bindu Pathak, Tanmaya Rao, Krishnamurthy Narasimha Shashidharaprasad, J. Lokanath, N.K. |
| description | Synthesis and single-crystal X-ray structural analyses of selected aminodideoxy sugars with different group substitutions at the C-2 position were carried out. Product formation and X-ray crystallographic determination of the products from C-2 substitution in both α and β anomers were studied. The observed variation in pyranose ring conformations in product compounds is explained in terms of C-2 substitution.
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| doi_str_mv | 10.1016/S0008-6215(02)00208-2 |
| format | article |
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| fulltext | fulltext |
| identifier | ISSN: 0008-6215 |
| ispartof | Carbohydrate research, 2002-09, Vol.337 (16), p.1507-1512 |
| issn | 0008-6215 1873-426X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_72039296 |
| source | ScienceDirect Journals |
| subjects | Amino sugars Amino Sugars - chemistry C-2 Substitution Carbohydrate Conformation Crystallography, X-Ray Deoxy Sugars - chemistry Magnetic Resonance Spectroscopy Models, Molecular Pyranose conformation Pyrans - chemistry Stereoisomerism Steric hindrance Structure-Activity Relationship α and β Anomers |
| title | Structural studies on C-2 substitution in a new set of synthetic aminodideoxy sugars: the steric bulk at C-2 influences the puckering of the pyranose ring |
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