A Two-Step Conversion of α,β-Unsaturated Ketones to Their α-Carbalkoxy or α-Carbamoyl Derivatives

Several enones are converted into their α-iodo derivatives in excellent yields and carbonylated with palladium catalysis in the presence of alcohol or amines to the α-carbonyl enones in satisfactory yields.

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Bibliographic Details
Published in:Journal of organic chemistry 2002-09, Vol.67 (18), p.6568-6570
Main Authors: Souza, Fabio E. S, Sutherland, Hamish S, Carlini, Rina, Rodrigo, Russell
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
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Description
Summary:Several enones are converted into their α-iodo derivatives in excellent yields and carbonylated with palladium catalysis in the presence of alcohol or amines to the α-carbonyl enones in satisfactory yields.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo020081c