A layered tin(II) phosphonate, [Sn(C6H5O3P)]n

Poly­[tin(II)‐μ‐phenyl­phospho­nato], [Sn(C6H5O3P)]n, was synthesized solvothermally at 423 K and crystallized in the monoclinic system, space group Cc. The inorganic layers consist of alternating pyramidal Sn and tetrahedral P centers, joined by doubly bridging O atoms. The corner‐sharing SnO3 and...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2001-09, Vol.57 (9), p.1051-1052
Main Authors: Lansky, David E., Zavalij, Peter Y., Oliver, Scott R. J.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:Poly­[tin(II)‐μ‐phenyl­phospho­nato], [Sn(C6H5O3P)]n, was synthesized solvothermally at 423 K and crystallized in the monoclinic system, space group Cc. The inorganic layers consist of alternating pyramidal Sn and tetrahedral P centers, joined by doubly bridging O atoms. The corner‐sharing SnO3 and PO3C6H5 polyhedra define a corrugated layer of six‐membered rings. The layers are connected along the unique b axis by interdigitated phenyl rings of the phenyl­phospho­nate groups.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270101010034