Catalytic Asymmetric Conjugate Addition of Nitroalkanes to Cycloalkenones

Nitroalkanes add to cyclic and acyclic enones in an enantioselective manner in the presence of catalytic quantities of l-proline and trans-2,5-dimethylpiperazine as excess additive.

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Bibliographic Details
Published in:Organic letters 2000-09, Vol.2 (19), p.2975-2978
Main Authors: Hanessian, Stephen, Pham, Vinh
Format: Article
Language:English
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Description
Summary:Nitroalkanes add to cyclic and acyclic enones in an enantioselective manner in the presence of catalytic quantities of l-proline and trans-2,5-dimethylpiperazine as excess additive.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol000170g