2-Amidopyrroles and 2,5-Diamidopyrroles as Simple Anion Binding Agents

Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anion...

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Bibliographic Details
Published in:Journal of organic chemistry 2001-11, Vol.66 (23), p.7849-7853
Main Authors: Gale, Philip A, Camiolo, Salvatore, Tizzard, Graham J, Chapman, Christopher P, Light, Mark E, Coles, Simon J, Hursthouse, Michael B
Format: Article
Language:English
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Summary:Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anions has been demonstrated by 1H NMR titration techniques.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo016020g