Two-Dimensional Gas Chromatography and Trilinear Partial Least Squares for the Quantitative Analysis of Aromatic and Naphthene Content in Naphtha

• Published in: Analytical chemistry (Washington) 2001-12, Vol.73 (23), p.5677-5682
• Main Authors: Prazen, Bryan J, Johnson, Kevin J, Weber, Andrew, Synovec, Robert E
• Format: Article
• Language: English
• Subjects: Analytical chemistry; Applied sciences; Chemicals; Chemistry; Chromatographic methods and physical methods associated with chromatography; Crude oil, natural gas and petroleum products; Energy; Exact sciences and technology; Fuels; Gas chromatographic methods; Petroleum; Petroleum products, gas and fuels. Motor fuels, lubricants and asphalts
• ISSN: 0003-2700; 1520-6882
• DOI: 10.1021/ac010637g

Quantitative analysis of naphtha samples is demonstrated using comprehensive two-dimensional gas chromatography (GC × GC) and chemometrics. This work is aimed at providing a GC system for the quantitative and qualitative analysis of complex process streams for process monitoring and control. The high-speed GC × GC analysis of naphtha is accomplished through short GC columns, high carrier gas velocities, and partial chromatographic peak resolution followed by multivariate quantitative analysis. Six min GC × GC separations are analyzed with trilinear partial least squares (tri-PLS) to predict the aromatic and naphthene (cycloalkanes) content of naphtha samples. The 6-min GC × GC separation time is over 16 times faster than a single-GC-column standard method in which a single-column separation resolves the aromatic and naphthene compounds in naphtha and predicts the aromatic and naphthene percent concentrations through addition of the resolved signals. Acceptable quantitative precision is provided by GC × GC/tri-PLS.