Bismuth(V) iron(III) tris(phosphate) oxide

BiV0.4Fe3IIIO(PO4)3 crystallizes with two Fe atoms (one on an inversion centre and one on a mirror plane) displaying octahedral geometry and a third Fe atom (on a mirror plane) with trigonal bipyramidal coordination. Fe atoms are seen in oxy­gen‐bridged chains. BiV atoms are found in the interstitia...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-11, Vol.56 (11), p.1292-1293
Main Authors: Benabad, Aicha, Bakhous, Karima, Cherkaoui, Fatima, Holt, Elizabeth M.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Physics
Salts
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:BiV0.4Fe3IIIO(PO4)3 crystallizes with two Fe atoms (one on an inversion centre and one on a mirror plane) displaying octahedral geometry and a third Fe atom (on a mirror plane) with trigonal bipyramidal coordination. Fe atoms are seen in oxy­gen‐bridged chains. BiV atoms are found in the interstitial sites between these chains. Bi shows sevenfold coordination, with Bi—O distances between 2.357 (7) and 2.529 (6) Å.
ISSN:0108-2701
1600-5759
DOI:10.1107/S010827010000977X