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Control over the Structure of Ice and Water by Block Copolymer Additives

Antifreeze proteins protecting against ice crystallization have biomimetic analogons in block copolymers poly(ethylene oxide)–poly[2‐(2‐hydroxyethyl)ethylene] and its partially phosphorylated derivative. Both polymers influence the structure of liquid and solid water to a greater extent than the pro...

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Published in:	Chemphyschem 2002-01, Vol.3 (1), p.119-123
Main Authors:	Mastai, Yitzhak, Rudloff, Jan, Cölfen, Helmut, Antonietti, Markus
Format:	Article
Language:	English
Subjects:	Antifreeze Proteins - chemistry Applied sciences biomimetics Calorimetry, Differential Scanning Cold Temperature Cross-disciplinary physics: materials science rheology Crystallization double hydrophilic block copolymers Exact sciences and technology Growth from solutions Ice Materials science Methods of crystal growth physics of crystal growth Molecular Mimicry Molecular Structure Organic polymers Physicochemistry of polymers Physics Polymers - chemistry Properties and characterization proteins Special properties (catalyst, reagent or carrier) Water - chemistry X-Ray Diffraction
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creator	Mastai, Yitzhak Rudloff, Jan Cölfen, Helmut Antonietti, Markus
description	Antifreeze proteins protecting against ice crystallization have biomimetic analogons in block copolymers poly(ethylene oxide)–poly[2‐(2‐hydroxyethyl)ethylene] and its partially phosphorylated derivative. Both polymers influence the structure of liquid and solid water to a greater extent than the proteins, as shown by an excess increase of the average water density (as shown in the graph), water viscosity changes, additional exothermic enthalpic transitions close to the freezing point, as well as changes of the ice unit cell.
doi_str_mv	10.1002/1439-7641(20020118)3:1<119::AID-CPHC119>3.0.CO;2-R
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subjects	Antifreeze Proteins - chemistry Applied sciences biomimetics Calorimetry, Differential Scanning Cold Temperature Cross-disciplinary physics: materials science rheology Crystallization double hydrophilic block copolymers Exact sciences and technology Growth from solutions Ice Materials science Methods of crystal growth physics of crystal growth Molecular Mimicry Molecular Structure Organic polymers Physicochemistry of polymers Physics Polymers - chemistry Properties and characterization proteins Special properties (catalyst, reagent or carrier) Water - chemistry X-Ray Diffraction
title	Control over the Structure of Ice and Water by Block Copolymer Additives
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