Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution

Hypsochromic or bathochromic? Depending upon the acceptor group (A=H, CN, CHO, NO2) the position and intensity of the absorption maxima of a series of substituted oligo(phenylenevinylene)s change (see picture). Supported by semi‐empirical calculations, the extent and direction of the shift (hypsochr...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2002-01, Vol.41 (2), p.292-295
Main Authors: Meier, Herbert, Gerold, Jürgen, Kolshorn, Heinz, Baumann, Wolfram, Bletz, Michael
Format: Article
Language:English
Subjects:
absorption
Charge transfer
Conjugation
donor-acceptor systems
Mathematical analysis
Maxima
Nitrogen dioxide
oligomers
Pictures
semiempirical calculations
Terminals
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 295
container_issue 2
container_start_page 292
container_title Angewandte Chemie International Edition
container_volume 41
creator Meier, Herbert
Gerold, Jürgen
Kolshorn, Heinz
Baumann, Wolfram
Bletz, Michael
description Hypsochromic or bathochromic? Depending upon the acceptor group (A=H, CN, CHO, NO2) the position and intensity of the absorption maxima of a series of substituted oligo(phenylenevinylene)s change (see picture). Supported by semi‐empirical calculations, the extent and direction of the shift (hypsochromic or bathochromic) is attributable to the opposing effects of length of conjugation and charge transfer.
doi_str_mv 10.1002/1521-3773(20020118)41:2<292::AID-ANIE292>3.0.CO;2-Q
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_72783422</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1701042879</sourcerecordid><originalsourceid>FETCH-LOGICAL-i3582-7caca192bb3e607128f4803561a01294c5a79a033b4d52ebb4f1619cb03e5e823</originalsourceid><addsrcrecordid>eNp9kV9v0zAUxS0EYmPwFVCfUPfg4nvtxE6HkEo2RqVp1cSgqC9XTuYyQ5qUOGH02-Oq7Xjj6f773fNwDmNnIEYgBL6FBIFLreUQ4ygAzKmCMb7DDMfjyfScT66nF3F4L0dilM_OkN88YcePX09jr6Tk2iRwxF6E8COqGCPS5-wIUGWgAI9ZPqv892a4vnf1pnK1--139TQMHnx3P7h17crXthqcN3XT8klZunXXtIPPfRE63_Wdb-qX7NnSVsG92tcT9uXjxW3-iV_NLqf55Ip7mRjkurSlhQyLQrpUaECzVEbIJAUrADNVJlZnVkhZqLsEXVGoJaSQlYWQLnEG5Ql7s9Ndt82v3oWOVj6Urqps7Zo-kEZtpMItOPwvCFqAUGh0FtHXe7QvVu6O1q1f2XZDB4ciMN8BD75ym393QduQaGs3be2mQ0ikgJBiLhQzon1GJElQPouHm8MqKvOdsg-d-_OobNuflGqpE5pfX9LCfP2QLr7NaSH_AjaFlyA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1701042879</pqid></control><display><type>article</type><title>Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution</title><source>Wiley</source><creator>Meier, Herbert ; Gerold, Jürgen ; Kolshorn, Heinz ; Baumann, Wolfram ; Bletz, Michael</creator><creatorcontrib>Meier, Herbert ; Gerold, Jürgen ; Kolshorn, Heinz ; Baumann, Wolfram ; Bletz, Michael</creatorcontrib><description>Hypsochromic or bathochromic? Depending upon the acceptor group (A=H, CN, CHO, NO2) the position and intensity of the absorption maxima of a series of substituted oligo(phenylenevinylene)s change (see picture). Supported by semi‐empirical calculations, the extent and direction of the shift (hypsochromic or bathochromic) is attributable to the opposing effects of length of conjugation and charge transfer.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/1521-3773(20020118)41:2&lt;292::AID-ANIE292&gt;3.0.CO;2-Q</identifier><identifier>PMID: 12491412</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>absorption ; Charge transfer ; Conjugation ; donor-acceptor systems ; Mathematical analysis ; Maxima ; Nitrogen dioxide ; oligomers ; Pictures ; semiempirical calculations ; Terminals</subject><ispartof>Angewandte Chemie International Edition, 2002-01, Vol.41 (2), p.292-295</ispartof><rights>Copyright © 2002 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12491412$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Meier, Herbert</creatorcontrib><creatorcontrib>Gerold, Jürgen</creatorcontrib><creatorcontrib>Kolshorn, Heinz</creatorcontrib><creatorcontrib>Baumann, Wolfram</creatorcontrib><creatorcontrib>Bletz, Michael</creatorcontrib><title>Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Hypsochromic or bathochromic? Depending upon the acceptor group (A=H, CN, CHO, NO2) the position and intensity of the absorption maxima of a series of substituted oligo(phenylenevinylene)s change (see picture). Supported by semi‐empirical calculations, the extent and direction of the shift (hypsochromic or bathochromic) is attributable to the opposing effects of length of conjugation and charge transfer.</description><subject>absorption</subject><subject>Charge transfer</subject><subject>Conjugation</subject><subject>donor-acceptor systems</subject><subject>Mathematical analysis</subject><subject>Maxima</subject><subject>Nitrogen dioxide</subject><subject>oligomers</subject><subject>Pictures</subject><subject>semiempirical calculations</subject><subject>Terminals</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNp9kV9v0zAUxS0EYmPwFVCfUPfg4nvtxE6HkEo2RqVp1cSgqC9XTuYyQ5qUOGH02-Oq7Xjj6f773fNwDmNnIEYgBL6FBIFLreUQ4ygAzKmCMb7DDMfjyfScT66nF3F4L0dilM_OkN88YcePX09jr6Tk2iRwxF6E8COqGCPS5-wIUGWgAI9ZPqv892a4vnf1pnK1--139TQMHnx3P7h17crXthqcN3XT8klZunXXtIPPfRE63_Wdb-qX7NnSVsG92tcT9uXjxW3-iV_NLqf55Ip7mRjkurSlhQyLQrpUaECzVEbIJAUrADNVJlZnVkhZqLsEXVGoJaSQlYWQLnEG5Ql7s9Ndt82v3oWOVj6Urqps7Zo-kEZtpMItOPwvCFqAUGh0FtHXe7QvVu6O1q1f2XZDB4ciMN8BD75ym393QduQaGs3be2mQ0ikgJBiLhQzon1GJElQPouHm8MqKvOdsg-d-_OobNuflGqpE5pfX9LCfP2QLr7NaSH_AjaFlyA</recordid><startdate>20020118</startdate><enddate>20020118</enddate><creator>Meier, Herbert</creator><creator>Gerold, Jürgen</creator><creator>Kolshorn, Heinz</creator><creator>Baumann, Wolfram</creator><creator>Bletz, Michael</creator><general>WILEY-VCH Verlag GmbH</general><general>WILEY‐VCH Verlag GmbH</general><scope>BSCLL</scope><scope>NPM</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>20020118</creationdate><title>Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution</title><author>Meier, Herbert ; Gerold, Jürgen ; Kolshorn, Heinz ; Baumann, Wolfram ; Bletz, Michael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3582-7caca192bb3e607128f4803561a01294c5a79a033b4d52ebb4f1619cb03e5e823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>absorption</topic><topic>Charge transfer</topic><topic>Conjugation</topic><topic>donor-acceptor systems</topic><topic>Mathematical analysis</topic><topic>Maxima</topic><topic>Nitrogen dioxide</topic><topic>oligomers</topic><topic>Pictures</topic><topic>semiempirical calculations</topic><topic>Terminals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meier, Herbert</creatorcontrib><creatorcontrib>Gerold, Jürgen</creatorcontrib><creatorcontrib>Kolshorn, Heinz</creatorcontrib><creatorcontrib>Baumann, Wolfram</creatorcontrib><creatorcontrib>Bletz, Michael</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meier, Herbert</au><au>Gerold, Jürgen</au><au>Kolshorn, Heinz</au><au>Baumann, Wolfram</au><au>Bletz, Michael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2002-01-18</date><risdate>2002</risdate><volume>41</volume><issue>2</issue><spage>292</spage><epage>295</epage><pages>292-295</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Hypsochromic or bathochromic? Depending upon the acceptor group (A=H, CN, CHO, NO2) the position and intensity of the absorption maxima of a series of substituted oligo(phenylenevinylene)s change (see picture). Supported by semi‐empirical calculations, the extent and direction of the shift (hypsochromic or bathochromic) is attributable to the opposing effects of length of conjugation and charge transfer.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><pmid>12491412</pmid><doi>10.1002/1521-3773(20020118)41:2&lt;292::AID-ANIE292&gt;3.0.CO;2-Q</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2002-01, Vol.41 (2), p.292-295
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_72783422
source Wiley
subjects absorption
Charge transfer
Conjugation
donor-acceptor systems
Mathematical analysis
Maxima
Nitrogen dioxide
oligomers
Pictures
semiempirical calculations
Terminals
title Oligo(phenylenevinylene)s with Terminal Donor-Acceptor Substitution
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T14%3A07%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Oligo(phenylenevinylene)s%20with%20Terminal%20Donor-Acceptor%20Substitution&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Meier,%20Herbert&rft.date=2002-01-18&rft.volume=41&rft.issue=2&rft.spage=292&rft.epage=295&rft.pages=292-295&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/1521-3773(20020118)41:2%3C292::AID-ANIE292%3E3.0.CO;2-Q&rft_dat=%3Cproquest_pubme%3E1701042879%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-i3582-7caca192bb3e607128f4803561a01294c5a79a033b4d52ebb4f1619cb03e5e823%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1701042879&rft_id=info:pmid/12491412&rfr_iscdi=true