Novel Nucleophilic Trifluoromethylation of Vicinal Diol Cyclic Sulfates

A novel method for highly regioselective and stereospecific nucleophilic trifluoromethylation of vicinal diol cyclic sulfates, using the reagent derived from reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented.

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Published in:Organic letters 2002-12, Vol.4 (26), p.4671-4672
Main Authors: Takechi, Naoto, Ait-Mohand, Samia, Medebielle, Maurice, Dolbier, William R
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Language:English
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creator Takechi, Naoto
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Dolbier, William R
description A novel method for highly regioselective and stereospecific nucleophilic trifluoromethylation of vicinal diol cyclic sulfates, using the reagent derived from reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented.
doi_str_mv 10.1021/ol0270374
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Novel Nucleophilic Trifluoromethylation of Vicinal Diol Cyclic Sulfates
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