A New Mononuclear Iron(III) Complex Containing a Peroxocarbonate Ligand

Stabilization of a peroxocarbonate ligand by formation of a five‐membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ‐hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2002-04, Vol.41 (7), p.1202-1205
Main Authors: Hashimoto, Koji, Nagatomo, Shigenori, Fujinami, Shuhei, Furutachi, Hideki, Ogo, Seiji, Suzuki, Masatatsu, Uehara, Akira, Maeda, Yonezo, Watanabe, Yoshihito, Kitagawa, Teizo
Format: Article
Language:English
Subjects:
iron
oxygen activation
peroxo ligands
Raman spectroscopy
X-ray diffraction
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Stabilization of a peroxocarbonate ligand by formation of a five‐membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ‐hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn=quinaldic acid.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E