Unexpected isolation, and structural characterization, of a beta-hydrogen-containing sigma-alkylpalladium halide complex in the course of an intramolecular heck reaction. synthesis of polycyclic isoquinoline derivatives

The isolation of a stable beta-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-01 (2), p.272-273
Main Authors: Clique, Blandine, Fabritius, Charles-Henry, Couturier, Cédric, Monteiro, Nuno, Balme, Geneviève
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:The isolation of a stable beta-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.
ISSN:1359-7345
DOI:10.1039/b211856b