A novel role of zeolite NaY in the thermal reaction of alkyl aryl selenoxides in its supercages

Thermal reaction of alkyl aryl selenoxides in the presence of water or methanol in the supercage of zeolite NaY gave beta-hydroxy- or beta-methoxyalkyl aryl selenides, respectively, and NaY played a novel role to stabilize reactive ArSeOH and to separate an anion of -OH from a carbonium ion which wa...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-02 (4), p.498-499
Main Authors: Zhang, Wanxuan, Yu, Haitao, Gao, Yu, Meng, Jiben, Matsuura, Teruo
Format: Article
Language:English
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Summary:Thermal reaction of alkyl aryl selenoxides in the presence of water or methanol in the supercage of zeolite NaY gave beta-hydroxy- or beta-methoxyalkyl aryl selenides, respectively, and NaY played a novel role to stabilize reactive ArSeOH and to separate an anion of -OH from a carbonium ion which was simultaneously present with the -OH in a supercage.
ISSN:1359-7345
1364-548X
DOI:10.1039/b211833e