Vibrational study of the secondary thioamide function, the intramolecular resonance assisted and intermolecular hydrogen bonding in NN′-hydroxyalkyl dithiooxamides

The article describes the vibrational characterization of the secondary thioamide formation and especially a spectroscopical interesting study of different types of hydrogen bonding in NN′-dihydroxyalkyldithiooxamides.

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2003-04, Vol.59 (6), p.1359-1372
Main Authors: Desseyn, H.O, Blaton, N, Slootmaekers, B, Perlepes, S.P
Format: Article
Language:English
Subjects:
Ab initio calculations
Bromides - chemistry
Hydrogen Bonding
Models, Chemical
Potassium Compounds - chemistry
Secondary thioamides
Software
Spectrophotometry, Infrared - methods
Temperature
Thioamides - chemistry
Vibration
Vibrational spectra
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Description
Summary:The article describes the vibrational characterization of the secondary thioamide formation and especially a spectroscopical interesting study of different types of hydrogen bonding in NN′-dihydroxyalkyldithiooxamides.
ISSN:1386-1425
DOI:10.1016/S1386-1425(02)00336-0