An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water

A preformed oxime-carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active (> 99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased ac...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-03 (5), p.606-607
Main Authors: Baleizão, Carlos, Corma, Avelino, García, Hermenegildo, Leyva, Antonio
Format: Article
Language:English
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Summary:A preformed oxime-carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active (> 99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased activity.
ISSN:1359-7345
1364-548X
DOI:10.1039/b211742h