Synthesis and spectral characterization of novel compounds derived from 1,10-phenanthroline, lead(II) and tetrabutylammonium tetrafluoroborate

On interacting 1,10-phenanthroline (phen) with tetrabutylammonium tetrafluoroborate (Bu 4N·BF 4) two novel compounds have been obtained. These are the 1:1 adduct (phen)·(Bu 4N·BF 4) and the complex Pb(phen)(Bu 4N·BF 4) 3(NO 3) 2. The synthesized substances have been characterized by UV, IR and Raman...

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2003-05, Vol.59 (7), p.1655-1662
Main Authors: Atanassova, Maria S, Dimitrov, Georgi D
Format: Article
Language:English
Subjects:
1,10-Phenanthroline
Adduct
Borates - chemical synthesis
Borates - chemistry
Lead - chemistry
Lead complexes
Magnetic Resonance Spectroscopy
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phenanthrolines - chemistry
Quaternary Ammonium Compounds - chemical synthesis
Quaternary Ammonium Compounds - chemistry
Spectrophotometry, Infrared
Spectrophotometry, Ultraviolet
Spectrum Analysis, Raman
Tetrabutylammonium tetrafluoroborate
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Summary:On interacting 1,10-phenanthroline (phen) with tetrabutylammonium tetrafluoroborate (Bu 4N·BF 4) two novel compounds have been obtained. These are the 1:1 adduct (phen)·(Bu 4N·BF 4) and the complex Pb(phen)(Bu 4N·BF 4) 3(NO 3) 2. The synthesized substances have been characterized by UV, IR and Raman spectroscopy as well as by 1H- and 19F-NMR spectroscopy.
ISSN:1386-1425
DOI:10.1016/S1386-1425(02)00397-9