Synthesis of CDE and BCDE Molecular Fragments of the Limonoids Havanensin and Azadiradione

A new approach to the synthesis of CDE and BCDE molecular fragments of the limonoids havanensin and azadiradione has been achieved from cyclocitral and drimenal in seven steps in overall yields of 20 and 9%, respectively.

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Bibliographic Details
Published in:Journal of organic chemistry 2003-05, Vol.68 (9), p.3585-3592
Main Authors: FERNANDEZ-MATEOS, A, MATEOS BURON, L, DE LA NAVA, E. M, RUBIO GONZALEZ, R
Format: Article
Language:English
Subjects:
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Catalysis
Chemistry
Combinatorial Chemistry Techniques
Cyclization
Exact sciences and technology
Indicators and Reagents
Limonins - analysis
Limonins - chemical synthesis
Molecular Structure
Nuclear Magnetic Resonance, Biomolecular
Organic chemistry
Preparations and properties
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Description
Summary:A new approach to the synthesis of CDE and BCDE molecular fragments of the limonoids havanensin and azadiradione has been achieved from cyclocitral and drimenal in seven steps in overall yields of 20 and 9%, respectively.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo0205311