The Double N-Arylation of Primary Amines: Toward Multisubstituted Carbazoles with Unique Optical Properties

A powerful method: A variety of sterically crowded, substituted carbazoles have been prepared from anilines and biphenyl compounds (see scheme). The method enabled the preparation of 2,2′‐dicarbazolyl‐1,1′‐biaryl compounds, which show excimer (or exciplex) emissions with significant solvent dependen...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2003-05, Vol.42 (18), p.2051-2053
Main Authors: Nozaki, Kyoko, Takahashi, Keita, Nakano, Koji, Hiyama, Tamejiro, Tang, Hong-Zhi, Fujiki, Michiya, Yamaguchi, Shigehiro, Tamao, Kohei
Format: Article
Language:English
Subjects:
biaryls
luminescence
nitrogen heterocycles
palladium
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A powerful method: A variety of sterically crowded, substituted carbazoles have been prepared from anilines and biphenyl compounds (see scheme). The method enabled the preparation of 2,2′‐dicarbazolyl‐1,1′‐biaryl compounds, which show excimer (or exciplex) emissions with significant solvent dependency.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200250648