Stereoselective formation of dinuclear complexes with anomalous CD spectra

A novel chiral tetradentate Schiff base ligand forms dinuclear lambda,lambda-[M2L2Cl2]2+ complexes with high diastereoselectivity; the complexes exhibit anomalous CD spectra due to exciton coupling of chromophores located on different metal centres.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-05 (9), p.1064-1065
Main Authors: Telfer, Shane G, Kuroda, Reiko, Sato, Tomohiro
Format: Article
Language:English
Online Access:Get full text
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Summary:A novel chiral tetradentate Schiff base ligand forms dinuclear lambda,lambda-[M2L2Cl2]2+ complexes with high diastereoselectivity; the complexes exhibit anomalous CD spectra due to exciton coupling of chromophores located on different metal centres.
ISSN:1359-7345
DOI:10.1039/b301267k