Bipyridyl Derivatives as Photomemory Devices: A Comparative Electronic-Structure Study

• Published in: Chemistry : a European journal 2010-06, Vol.16 (22), p.6693-6703
• Main Authors: Ortiz-Sánchez, Juan Manuel, Gelabert, Ricard, Moreno, Miquel, Lluch, José M., Anglada, Josep M., Bofill, Josep M.
• Format: Article
• Language: English
• Subjects: 2,2'-Dipyridyl - analogs & derivatives; 2,2'-Dipyridyl - chemistry; bipyridyls; Chemistry; computer chemistry; Computer Simulation; conical intersections; Density functional theory; Derivatives; Devices; Electrochemistry - methods; Electronics - methods; Fluorescence; Mathematical analysis; Models, Molecular; Molecular Structure; Photochemical; Photochemistry; Potential energy; proton transfer; reaction mechanisms; Wavelengths
• ISSN: 0947-6539; 1521-3765
• DOI: 10.1002/chem.200903440

The two isoelectronic bipyridyl derivatives [2,2′‐bipyridyl]‐3,3′‐diamine (BP(NH2)2) and [2,2′‐bipyridyl]‐3,3′‐diol (BP(OH)2) are experimentally known to undergo very different excited‐state double proton transfer processes that result in fluorescence quantum yields that differ by four orders of magnitude. Such differences have been theoretically explained in terms of topographical features in the potential energy surface and the likely presence of conical intersections. The hypothetical hybrid compound [2,2′‐bipyridyl]‐3‐amin‐3′‐ol (BP(OH)(NH2)) presents intermediate photochemical features of its “ancestors”. In this report we analyze the photochemical properties of a whole family of “dark” (not fluorescent) states that can be accessed from each bipyridyl derivative upon irradiation of light of a given wavelength and their potential application as photomemory devices. In the light of our density functional theory (DFT), time‐dependent DFT (TDDFT), and complete active space self‐consistent field (CASSCF) calculations, BP(NH2)2 is the more likely candidate to become a photomemory device. Photomemory devices: The photochemical behavior of three isoelectronic compounds, [2,2′‐bipyridyl]‐3,3′‐diamine, [2,2′‐bipyridyl]‐3,3′‐diol, and the hybrid [2,2′‐bipyridyl]‐3‐amine‐3′‐ol (see figure), has been theoretically analyzed to assess their potential applicability as photomemory devices. Other, more speculative, potential applications are also envisaged.