Efficient and Rapid Synthesis of Oligo(p-phenylenevinylene) via Iterative Coherent Approach

A general and controlled bidirectional growth strategy enables a very rapid and efficient construction of OPV compounds possessing functional groups such as aldehyde and mercapto groups at both ends. The strategy employs only one reaction type with high yields and stereoselectivities to grow the con...

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Bibliographic Details
Published in:Journal of organic chemistry 2003-05, Vol.68 (11), p.4417-4421
Main Authors: Xue, Cuihua, Luo, Fen-Tair
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
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Summary:A general and controlled bidirectional growth strategy enables a very rapid and efficient construction of OPV compounds possessing functional groups such as aldehyde and mercapto groups at both ends. The strategy employs only one reaction type with high yields and stereoselectivities to grow the conjugated chains, eliminating the need for protecting groups in the overall intermediates.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo026907s