Determining the size-dependent structure of ligand-free gold-cluster ions

Ligand-free metal clusters can be prepared over a wide size range, but only in comparatively small amounts. Determining their size-dependent properties has therefore required the development of experimental methods that allow characterization of sample sizes comprising only a few thousand mass-selec...

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Published in:Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 2010-03, Vol.368 (1915), p.1211-1243
Main Authors: Schooss, Detlef, Weis, Patrick, Hampe, Oliver, Kappes, Manfred M.
Format: Article
Language:English
Subjects:
Adsorption
Anions
Atoms
Binding energy
Cations
Electron Diffraction
Electronic structure
Electrons
Gold Clusters
Ion Mobility
Ions
Isomers
Kinetics
Optical Properties
Review
Structure
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cited_by cdi_FETCH-LOGICAL-c564t-e94f3d835a1dcfd38aba999fb37f2d62d7b1cea20bfe5c7c26d59c5396f8c8693
cites cdi_FETCH-LOGICAL-c564t-e94f3d835a1dcfd38aba999fb37f2d62d7b1cea20bfe5c7c26d59c5396f8c8693
container_end_page 1243
container_issue 1915
container_start_page 1211
container_title Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences
container_volume 368
creator Schooss, Detlef
Weis, Patrick
Hampe, Oliver
Kappes, Manfred M.
description Ligand-free metal clusters can be prepared over a wide size range, but only in comparatively small amounts. Determining their size-dependent properties has therefore required the development of experimental methods that allow characterization of sample sizes comprising only a few thousand mass-selected particles under well-defined collision-free conditions. In this review, we describe the application of these methods to the geometric structural determination of Au+n and Au−n with n = 3-20. Geometries were assigned by comparing experimental data, primarily from ion-mobility spectrometry and trapped ion electron diffraction, to structural models from quantum chemical calculations.
doi_str_mv 10.1098/rsta.2009.0269
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source JSTOR Archival Journals and Primary Sources Collection; Royal Society Publishing Jisc Collections Royal Society Journals Read & Publish Transitional Agreement 2025 (reading list)
subjects Adsorption
Anions
Atoms
Binding energy
Cations
Electron Diffraction
Electronic structure
Electrons
Gold Clusters
Ion Mobility
Ions
Isomers
Kinetics
Optical Properties
Review
Structure
title Determining the size-dependent structure of ligand-free gold-cluster ions
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