Facile dihydrogen release from phosphino-borinate ester Lewis pairs

New phosphino-borinate ester Lewis pairs of the type (t)Bu(2)PCH(2)C(R)(2)OB(C(6)F(5))(2) (R = Me or CF(3)) are synthesised from the corresponding phosphino-alcohol and HB(C(6)F(5))(2). Dihydrogen release from the zwitterionic (t)Bu(2)PHCH(2)C(R)(2)OBH(C(6)F(5))(2) is facile.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (27), p.6184-6186
Main Authors: Chapman, Andy M, Haddow, Mairi F, Orton, Jonathan P H, Wass, Duncan F
Format: Article
Language:English
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Summary:New phosphino-borinate ester Lewis pairs of the type (t)Bu(2)PCH(2)C(R)(2)OB(C(6)F(5))(2) (R = Me or CF(3)) are synthesised from the corresponding phosphino-alcohol and HB(C(6)F(5))(2). Dihydrogen release from the zwitterionic (t)Bu(2)PHCH(2)C(R)(2)OBH(C(6)F(5))(2) is facile.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt00513d