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A Templateless, Surfactantless, Simple Electrochemical Route to a Dendritic Gold Nanostructure and Its Application to Oxygen Reduction
A templateless, surfactantless, simple electrochemical route to prepare dendritic gold nanostructure is reported. The morphology, composition, and structure of as-prepared dendritic gold nanostructure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), e...
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Published in: | Langmuir 2010-05, Vol.26 (10), p.7627-7631 |
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creator | Xu, Xiaolong Jia, Jianbo Yang, Xiurong Dong, Shaojun |
description | A templateless, surfactantless, simple electrochemical route to prepare dendritic gold nanostructure is reported. The morphology, composition, and structure of as-prepared dendritic gold nanostructure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The whole nanostructure was constructed by pristine metallic gold. The formation mechanism related to experimental conditions was discussed. The synthesis promises indium tin oxide (ITO) electrode can be easily modified with the dendritic pristine gold nanostructure. The as-prepared modified ITO electrode has excellent catalytic activity to oxygen reduction in neutral KCl solution. |
doi_str_mv | 10.1021/la904245q |
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The morphology, composition, and structure of as-prepared dendritic gold nanostructure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The whole nanostructure was constructed by pristine metallic gold. The formation mechanism related to experimental conditions was discussed. The synthesis promises indium tin oxide (ITO) electrode can be easily modified with the dendritic pristine gold nanostructure. The as-prepared modified ITO electrode has excellent catalytic activity to oxygen reduction in neutral KCl solution.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la904245q</identifier><identifier>PMID: 20099828</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Catalysis ; Chemistry ; Colloidal state and disperse state ; Dendrimers - chemical synthesis ; Dendrimers - chemistry ; Electrochemistry ; Electrochemistry: Charge Transfer, Electrocatalysis, Kinetics, Bioelectrochemistry ; Exact sciences and technology ; General and physical chemistry ; Gold - chemistry ; Metal Nanoparticles - chemistry ; Oxidation-Reduction ; Oxygen - chemistry ; Particle Size ; Surface physical chemistry ; Surface Properties ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Langmuir, 2010-05, Vol.26 (10), p.7627-7631</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a344t-7c68dd315ab039d3fc64487c1e41e85fef670a3720213c955ed2ce927bf07703</citedby><cites>FETCH-LOGICAL-a344t-7c68dd315ab039d3fc64487c1e41e85fef670a3720213c955ed2ce927bf07703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27900,27901</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22796102$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20099828$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Xiaolong</creatorcontrib><creatorcontrib>Jia, Jianbo</creatorcontrib><creatorcontrib>Yang, Xiurong</creatorcontrib><creatorcontrib>Dong, Shaojun</creatorcontrib><title>A Templateless, Surfactantless, Simple Electrochemical Route to a Dendritic Gold Nanostructure and Its Application to Oxygen Reduction</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>A templateless, surfactantless, simple electrochemical route to prepare dendritic gold nanostructure is reported. The morphology, composition, and structure of as-prepared dendritic gold nanostructure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The whole nanostructure was constructed by pristine metallic gold. The formation mechanism related to experimental conditions was discussed. The synthesis promises indium tin oxide (ITO) electrode can be easily modified with the dendritic pristine gold nanostructure. The as-prepared modified ITO electrode has excellent catalytic activity to oxygen reduction in neutral KCl solution.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Dendrimers - chemical synthesis</subject><subject>Dendrimers - chemistry</subject><subject>Electrochemistry</subject><subject>Electrochemistry: Charge Transfer, Electrocatalysis, Kinetics, Bioelectrochemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Gold - chemistry</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Oxidation-Reduction</subject><subject>Oxygen - chemistry</subject><subject>Particle Size</subject><subject>Surface physical chemistry</subject><subject>Surface Properties</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Xiaolong</creatorcontrib><creatorcontrib>Jia, Jianbo</creatorcontrib><creatorcontrib>Yang, Xiurong</creatorcontrib><creatorcontrib>Dong, Shaojun</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Xiaolong</au><au>Jia, Jianbo</au><au>Yang, Xiurong</au><au>Dong, Shaojun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Templateless, Surfactantless, Simple Electrochemical Route to a Dendritic Gold Nanostructure and Its Application to Oxygen Reduction</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2010-05-18</date><risdate>2010</risdate><volume>26</volume><issue>10</issue><spage>7627</spage><epage>7631</epage><pages>7627-7631</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>A templateless, surfactantless, simple electrochemical route to prepare dendritic gold nanostructure is reported. The morphology, composition, and structure of as-prepared dendritic gold nanostructure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The whole nanostructure was constructed by pristine metallic gold. The formation mechanism related to experimental conditions was discussed. The synthesis promises indium tin oxide (ITO) electrode can be easily modified with the dendritic pristine gold nanostructure. The as-prepared modified ITO electrode has excellent catalytic activity to oxygen reduction in neutral KCl solution.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>20099828</pmid><doi>10.1021/la904245q</doi><tpages>5</tpages></addata></record> |
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subjects | Catalysis Chemistry Colloidal state and disperse state Dendrimers - chemical synthesis Dendrimers - chemistry Electrochemistry Electrochemistry: Charge Transfer, Electrocatalysis, Kinetics, Bioelectrochemistry Exact sciences and technology General and physical chemistry Gold - chemistry Metal Nanoparticles - chemistry Oxidation-Reduction Oxygen - chemistry Particle Size Surface physical chemistry Surface Properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | A Templateless, Surfactantless, Simple Electrochemical Route to a Dendritic Gold Nanostructure and Its Application to Oxygen Reduction |
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