Pressure-induced Jahn-Teller switching in a Mn12 nanomagnet

Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2010, Vol.46 (11), p.1881-1883
Main Authors: Parois, Pascal, Moggach, Stephen A, Sanchez-Benitez, Javier, Kamenev, Konstantin V, Lennie, Alistair R, Warren, John E, Brechin, Euan K, Parsons, Simon, Murrie, Mark
Format: Article
Language:English
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Summary:Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.
ISSN:1359-7345
1364-548X
DOI:10.1039/b923962f