Solid/Liquid Phase Diagram of the Ammonium Sulfate/Malonic Acid/Water System

We have studied the thermodynamic properties of the ammonium sulfate/malonic acid/water system using differential scanning calorimetry and infrared spectroscopy of thin films. Using the results from our experiments and literature data, we have created a solid/liquid phase diagram of the ammonium sul...

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Bibliographic Details
Published in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2010-04, Vol.114 (12), p.4282-4288
Main Authors: Beyer, Keith D, Schroeder, Jason, Palet, Benjamin
Format: Article
Language:English
Subjects:
A: Atmospheric, Environmental and Green Chemistry
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Summary:We have studied the thermodynamic properties of the ammonium sulfate/malonic acid/water system using differential scanning calorimetry and infrared spectroscopy of thin films. Using the results from our experiments and literature data, we have created a solid/liquid phase diagram of the ammonium sulfate/malonic acid/water system for temperatures below 300 K. We also compare our results to the predictions of the aerosol inorganics model (AIM).
ISSN:1089-5639
1520-5215
DOI:10.1021/jp100493d