Superior Anion-Binding Properties of a Cryptand-like Oligopyrrolic Macrocycle

Recognition by strapped system: Cryptand‐type calix[4]pyrrole are shown to exhibit a highly enhanced affinity towards anionic guests as compared to other reported calix[4]pyrroles (see figure). The results obtained provide some insights as to how calix[4]pyrrole‐based anion receptors may be designed...

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Published in:Chemistry, an Asian journal an Asian journal, 2010-04, Vol.5 (4), p.768-772
Main Authors: Hong, Seong-Jin, Yoo, Jaeduk, Yoon, Dae-Wi, Yoon, Juyoung, Kim, Jong Seung, Lee, Chang-Hee
Format: Article
Language:English
Subjects:
anion-binding
anion-π interaction
cryptand calixpyrrole
enhanced anion affinity
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cited_by cdi_FETCH-LOGICAL-c4488-af8495830d92070c1ee1b74bf12a5c47504fd5190467b9b26261e954d04c2e0d3
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container_title Chemistry, an Asian journal
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creator Hong, Seong-Jin
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description Recognition by strapped system: Cryptand‐type calix[4]pyrrole are shown to exhibit a highly enhanced affinity towards anionic guests as compared to other reported calix[4]pyrroles (see figure). The results obtained provide some insights as to how calix[4]pyrrole‐based anion receptors may be designed to achieve higher affinity and selectivity.
doi_str_mv 10.1002/asia.200900518
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source Wiley-Blackwell Read & Publish Collection
subjects anion-binding
anion-π interaction
cryptand calixpyrrole
enhanced anion affinity
title Superior Anion-Binding Properties of a Cryptand-like Oligopyrrolic Macrocycle
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