Ring-Rearrangement Metathesis of Cyclopropenes: Synthesis of Heterocycles

Cyclopropenes substituted by an unsaturated side chain have been successfully involved in ring-rearrangement metatheses leading to heterocyclic compounds, thereby expanding the synthetic potential of metathesis reactions with this class of highly strained cycloalkenes.

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Bibliographic Details
Published in:Organic letters 2010-01, Vol.12 (2), p.248-251
Main Authors: Miege, Frédéric, Meyer, Christophe, Cossy, Janine
Format: Article
Language:English
Subjects:
Cyclization
Cyclopropanes - chemical synthesis
Cyclopropanes - chemistry
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
Molecular Structure
Stereoisomerism
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Description
Summary:Cyclopropenes substituted by an unsaturated side chain have been successfully involved in ring-rearrangement metatheses leading to heterocyclic compounds, thereby expanding the synthetic potential of metathesis reactions with this class of highly strained cycloalkenes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol9025606