X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles

The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorp...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 2009-12, Vol.131 (24), p.244716-244716
Main Authors: Bayindir, Z, Duchesne, P N, Cook, S C, MacDonald, M A, Zhang, P
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3
cites cdi_FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3
container_end_page 244716
container_issue 24
container_start_page 244716
container_title The Journal of chemical physics
container_volume 131
creator Bayindir, Z
Duchesne, P N
Cook, S C
MacDonald, M A
Zhang, P
description The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorption spectroscopy (XAS), and theoretical projected local density of states (l-DOS) calculations. Transmission electron microscopy and XPS composition analysis indicated that the three NPs were all very small (1-2 nm), the NP size decreasing in the order of Pt-TA>Pt-PA approximately Pt-SR. All the three samples showed a positive Pt 4f binding energy (BE) shift relative to that of the bulk, in the order of bulk
doi_str_mv 10.1063/1.3276917
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_733699950</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>733699950</sourcerecordid><originalsourceid>FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3</originalsourceid><addsrcrecordid>eNo9kMtKA0EQRRtRTIwu_AHpnbiY2M-Z6aUEXxBwo-BuqPTUkJF52Q_Qv7dNoqviVh0OxSXkkrMlZ7m85Uspitzw4ojMOStNlgI7JnPGBM9MzvIZOfP-gzHGC6FOyUwwpk0i5-TrPXPwTf2ENrjR23FKIcS6RU_HgYYtUh9dAzbN4KIN0UFH7RYc2ICu9aG1nsJQU-x2iqG1dHLjhC7sHA2dOgjtEHs6wDBOkPa2Q39OThroPF4c5oK8Pdy_rp6y9cvj8-punVlRqpAJCVjWDSgBQhaiELVS0GiO6ax1w_PSbMBIBbkoNMoahFZSlbbcyEJDCXJBrvfe9NRnRB-qvvUWuw4GHKOvCilzY4xmibzZkzYV4R021eTaHtx3xVn123PFq0PPib06WOOmx_qf_CtW_gA_TXpg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733699950</pqid></control><display><type>article</type><title>X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><source>AIP Journals (American Institute of Physics)</source><creator>Bayindir, Z ; Duchesne, P N ; Cook, S C ; MacDonald, M A ; Zhang, P</creator><creatorcontrib>Bayindir, Z ; Duchesne, P N ; Cook, S C ; MacDonald, M A ; Zhang, P</creatorcontrib><description>The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorption spectroscopy (XAS), and theoretical projected local density of states (l-DOS) calculations. Transmission electron microscopy and XPS composition analysis indicated that the three NPs were all very small (1-2 nm), the NP size decreasing in the order of Pt-TA&gt;Pt-PA approximately Pt-SR. All the three samples showed a positive Pt 4f binding energy (BE) shift relative to that of the bulk, in the order of bulk&lt;Pt-TA&lt;Pt-PA&lt;Pt-SR. The origin of the BE shift was elucidated by XAS and deconvolution of the Pt 4f XPS peak, indicating that the observed BE shifts were largely associated with the initial state effect (i.e., nanosize and surface structure). The surface and size effects on the electronic behavior of Pt were further studied by valence band XPS and the results were interpreted with calculated d-DOS of three Pt(55) model clusters with varied surface structures. Finally, the implication of these results on tuning the electronic properties of Pt NPs with size, surface, and alloying effects was discussed.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.3276917</identifier><identifier>PMID: 20059108</identifier><language>eng</language><publisher>United States</publisher><ispartof>The Journal of chemical physics, 2009-12, Vol.131 (24), p.244716-244716</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3</citedby><cites>FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,782,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20059108$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bayindir, Z</creatorcontrib><creatorcontrib>Duchesne, P N</creatorcontrib><creatorcontrib>Cook, S C</creatorcontrib><creatorcontrib>MacDonald, M A</creatorcontrib><creatorcontrib>Zhang, P</creatorcontrib><title>X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorption spectroscopy (XAS), and theoretical projected local density of states (l-DOS) calculations. Transmission electron microscopy and XPS composition analysis indicated that the three NPs were all very small (1-2 nm), the NP size decreasing in the order of Pt-TA&gt;Pt-PA approximately Pt-SR. All the three samples showed a positive Pt 4f binding energy (BE) shift relative to that of the bulk, in the order of bulk&lt;Pt-TA&lt;Pt-PA&lt;Pt-SR. The origin of the BE shift was elucidated by XAS and deconvolution of the Pt 4f XPS peak, indicating that the observed BE shifts were largely associated with the initial state effect (i.e., nanosize and surface structure). The surface and size effects on the electronic behavior of Pt were further studied by valence band XPS and the results were interpreted with calculated d-DOS of three Pt(55) model clusters with varied surface structures. Finally, the implication of these results on tuning the electronic properties of Pt NPs with size, surface, and alloying effects was discussed.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNo9kMtKA0EQRRtRTIwu_AHpnbiY2M-Z6aUEXxBwo-BuqPTUkJF52Q_Qv7dNoqviVh0OxSXkkrMlZ7m85Uspitzw4ojMOStNlgI7JnPGBM9MzvIZOfP-gzHGC6FOyUwwpk0i5-TrPXPwTf2ENrjR23FKIcS6RU_HgYYtUh9dAzbN4KIN0UFH7RYc2ICu9aG1nsJQU-x2iqG1dHLjhC7sHA2dOgjtEHs6wDBOkPa2Q39OThroPF4c5oK8Pdy_rp6y9cvj8-punVlRqpAJCVjWDSgBQhaiELVS0GiO6ax1w_PSbMBIBbkoNMoahFZSlbbcyEJDCXJBrvfe9NRnRB-qvvUWuw4GHKOvCilzY4xmibzZkzYV4R021eTaHtx3xVn123PFq0PPib06WOOmx_qf_CtW_gA_TXpg</recordid><startdate>20091228</startdate><enddate>20091228</enddate><creator>Bayindir, Z</creator><creator>Duchesne, P N</creator><creator>Cook, S C</creator><creator>MacDonald, M A</creator><creator>Zhang, P</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20091228</creationdate><title>X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles</title><author>Bayindir, Z ; Duchesne, P N ; Cook, S C ; MacDonald, M A ; Zhang, P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bayindir, Z</creatorcontrib><creatorcontrib>Duchesne, P N</creatorcontrib><creatorcontrib>Cook, S C</creatorcontrib><creatorcontrib>MacDonald, M A</creatorcontrib><creatorcontrib>Zhang, P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bayindir, Z</au><au>Duchesne, P N</au><au>Cook, S C</au><au>MacDonald, M A</au><au>Zhang, P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2009-12-28</date><risdate>2009</risdate><volume>131</volume><issue>24</issue><spage>244716</spage><epage>244716</epage><pages>244716-244716</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorption spectroscopy (XAS), and theoretical projected local density of states (l-DOS) calculations. Transmission electron microscopy and XPS composition analysis indicated that the three NPs were all very small (1-2 nm), the NP size decreasing in the order of Pt-TA&gt;Pt-PA approximately Pt-SR. All the three samples showed a positive Pt 4f binding energy (BE) shift relative to that of the bulk, in the order of bulk&lt;Pt-TA&lt;Pt-PA&lt;Pt-SR. The origin of the BE shift was elucidated by XAS and deconvolution of the Pt 4f XPS peak, indicating that the observed BE shifts were largely associated with the initial state effect (i.e., nanosize and surface structure). The surface and size effects on the electronic behavior of Pt were further studied by valence band XPS and the results were interpreted with calculated d-DOS of three Pt(55) model clusters with varied surface structures. Finally, the implication of these results on tuning the electronic properties of Pt NPs with size, surface, and alloying effects was discussed.</abstract><cop>United States</cop><pmid>20059108</pmid><doi>10.1063/1.3276917</doi><tpages>1</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2009-12, Vol.131 (24), p.244716-244716
issn 0021-9606
1089-7690
language eng
recordid cdi_proquest_miscellaneous_733699950
source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list); AIP Journals (American Institute of Physics)
title X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T02%3A25%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=X-ray%20spectroscopy%20studies%20on%20the%20surface%20structural%20characteristics%20and%20electronic%20properties%20of%20platinum%20nanoparticles&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Bayindir,%20Z&rft.date=2009-12-28&rft.volume=131&rft.issue=24&rft.spage=244716&rft.epage=244716&rft.pages=244716-244716&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.3276917&rft_dat=%3Cproquest_cross%3E733699950%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c284t-23ae8dfa42a237272d44af51ec2855f1689ba934a6275e3da254348c8b375a8a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=733699950&rft_id=info:pmid/20059108&rfr_iscdi=true