Hydrotelluration of aminoalkynes

Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-06 (11), p.1258-1259
Main Authors: Zeni, Gilson, Barros, Olga Soares do Rego, Moro, Angélica Venturini, Braga, Antonio Luiz, Peppe, Clovis
Format: Article
Language:English
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Summary:Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the amino group substituent.
ISSN:1359-7345
DOI:10.1039/b301857a