Organophosphorus reagents as extractants—part 3. Synergic effect of triphenyl phosphine oxide and bis(diphenyl phosphinyl) alkanes on extraction of iron(III) from thiocyanate medium with 2,4-pentdione

• Published in: Talanta (Oxford) 1992-06, Vol.39 (6), p.659-663
• Main Authors: Lobana, Tarlok S., Bhatia, Pushvinder K.
• Format: Article
• Language: English
• Subjects: Chemistry; Exact sciences and technology; Inorganic chemistry and origins of life; Kinetics and mechanism of reactions
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/0039-9140(92)80077-Q

The extraction of iron(III) from thiocyanate medium was carried out with a synergic combination of 2,4-pentdione (Hacac) and either triphenyl phosphine oxide (Ph 3 PO) or bis (diphenylphosphinyl) alkanes, Ph 2P(O)(CH 2) n ·P(O)PH 2 [ligand abbreviation, n: dpeO 2, 2; dpbO 2, 4]. Iron(III) was quantitatively separated from its binary mixture with chromium(III), manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II), mercury(II), lead(II), magnesium(II) and from steel samples. Copper(II) and silver(I) however, interfered. The percentage extraction was 99.0%. The respective extraction constants, K HA, K L or K syn, for the extracted species, [Fe(NCS)(acac) 2(H 2O)] (HA  Hacac), Fe(NCS) 3L 2 [L b Ph 3PO, dpeO 2 or dpbO 2], or Fe(NCS)(acac) 2L were found to be: K HA, 1.48 × 10 3, K L, 1.80 × 10 2 (L  Ph 3PO), 2.02 × 10 2 (L  dpeO 2 or dpbO 2) and K syn, 1.87 × 10 6 (L  Ph 3PO), 2.56 × 10 6 [L  dpeO 2 or dpbO 2].