Uranyl-selective PVC membrane electrodes based on some recently synthesized benzo-substituted macrocyclic diamides

Four different recently synthesized macrocyclic diamides were studied to characterize their abilities as uranyl ion carriers in PVC membrane electrodes. The electrodes based on macrocycle 1,18-diaza-3,4;15,16-dibenzo-5,8,11,14,21,24-hexaoxacyclohexaeicosane-2,17-dione resulted in a Nernstian respons...

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Published in:Talanta (Oxford) 2002-08, Vol.58 (2), p.237-246
Main Authors: Shamsipur, Mojtaba, Soleymanpour, Ahmad, Akhond, Morteza, Sharghi, Hashem, Massah, Ahmad Reza
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemistry
Electrochemical methods
Exact sciences and technology
Macrocyclic diamides
Potentiometry
PVC membrane
Uranyl ion-selective electrodes
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container_issue 2
container_start_page 237
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creator Shamsipur, Mojtaba
Soleymanpour, Ahmad
Akhond, Morteza
Sharghi, Hashem
Massah, Ahmad Reza
description Four different recently synthesized macrocyclic diamides were studied to characterize their abilities as uranyl ion carriers in PVC membrane electrodes. The electrodes based on macrocycle 1,18-diaza-3,4;15,16-dibenzo-5,8,11,14,21,24-hexaoxacyclohexaeicosane-2,17-dione resulted in a Nernstian response for UO 2 2+ ion over wide concentration ranges. The linear concentration range for the polymeric membrane electrode (PME) is 3.0×10 −6–8.2×10 −3 M with a detection limit of 2.2×10 −6 and that for the coated graphite electrode (CGE) is 5.0×10 −7–1.5×10 −3 M with a detection limit of 3.5×10 −7 M. The electrodes manifest advantages of low resistance, very fast response and, most importantly, good selectivities relative to a wide variety of other cations.
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subjects Analytical chemistry
Chemistry
Electrochemical methods
Exact sciences and technology
Macrocyclic diamides
Potentiometry
PVC membrane
Uranyl ion-selective electrodes
title Uranyl-selective PVC membrane electrodes based on some recently synthesized benzo-substituted macrocyclic diamides
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