On the determination of the free concentration of ligands

Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of...

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Bibliographic Details
Published in:Talanta (Oxford) 1992-06, Vol.39 (6), p.649-652
Main Authors: Placeres, J.C.Rodriguez, Alaejos, M.T.Sanz, Montelongo, F.J.Garcia
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Summary:Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of co-ordination systems.
ISSN:0039-9140
1873-3573
DOI:10.1016/0039-9140(92)80075-O