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Study of the degradation products of bromopropylate, chlordimeform, coumaphos, cymiazole, flumethrin and tau-fluvalinate in aqueous media

Degradation processes of bromopropylate, coumaphos, chlordimeform, cymiazole, flumethrin and fluvalinate in aqueous media have been studied by HPLC. Cymiazole is stable at any tested pH (1–11), while bromopropylate, flumethrin and coumaphos are unstable at basic pH and chlordimeform and fluvalinate...

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Bibliographic Details
Published in:Talanta (Oxford) 2000-06, Vol.52 (2), p.169-180
Main Authors: Corta, E., Bakkali, A., Barranco, A., Berrueta, L.A., Gallo, B., Vicente, F., Bogdanov, S.
Format: Article
Language:English
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Summary:Degradation processes of bromopropylate, coumaphos, chlordimeform, cymiazole, flumethrin and fluvalinate in aqueous media have been studied by HPLC. Cymiazole is stable at any tested pH (1–11), while bromopropylate, flumethrin and coumaphos are unstable at basic pH and chlordimeform and fluvalinate in neutral and basic media. The main degradation products have been identified by GC-MS. The reaction rate constants and half-lives were calculated and the effect of co-solvents on the rate and product profile was studied.
ISSN:0039-9140
1873-3573
DOI:10.1016/S0039-9140(00)00333-7