Cadmium Imidazolate Frameworks with Polymorphism, High Thermal Stability, and a Large Surface Area

Polymorphous cadmium 2‐substituent imidazolate frameworks (CdIFs) with high porosity and thermal stability have been realized (see figure). The use of cadmium results in the elongation of MN bonds and increased flexibility of the MN bond rotation resulting in polymorphism, high porosity, and therm...

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Bibliographic Details
Published in:Chemistry : a European journal 2010-01, Vol.16 (4), p.1137-1141
Main Authors: Tian, Yun-Qi, Yao, Shi-Yan, Gu, Dong, Cui, Ke-Hui, Guo, Dong-Wei, Zhang, Gao, Chen, Zhen-Xia, Zhao, Dong-Yuan
Format: Article
Language:English
Subjects:
cadmium imidazolates
Chemistry
gas adsorption
metal-organic frameworks
microporous materials
zeolites
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Summary:Polymorphous cadmium 2‐substituent imidazolate frameworks (CdIFs) with high porosity and thermal stability have been realized (see figure). The use of cadmium results in the elongation of MN bonds and increased flexibility of the MN bond rotation resulting in polymorphism, high porosity, and thermal stability.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200902729