Catalytic Upgrading of Bio-Oils by Ketonization

Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio‐oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketoniza...

Full description

Saved in:
Bibliographic Details
Published in:ChemSusChem 2009-01, Vol.2 (12), p.1121-1124
Main Authors: Gärtner, Christian A., Serrano-Ruiz, Juan Carlos, Braden, Drew J., Dumesic, James A.
Format: Article
Language:English
Subjects:
Acids - chemistry
alcohols
Alcohols - chemistry
biomass
Catalysis
esters
Esters - chemistry
ketones
Ketones - chemistry
Oils - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753
cites cdi_FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753
container_end_page 1124
container_issue 12
container_start_page 1121
container_title ChemSusChem
container_volume 2
creator Gärtner, Christian A.
Serrano-Ruiz, Juan Carlos
Braden, Drew J.
Dumesic, James A.
description Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio‐oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketonization of acids followed by ketonization of esters at higher conversions.
doi_str_mv 10.1002/cssc.200900178
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_733840331</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>733840331</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753</originalsourceid><addsrcrecordid>eNqFkM1PwjAYhxujEUWvHs1ungbtun4ddSoYCCQC0VvTdh2pjg3XEZ1_vZAR9ObpfQ_P7zk8AFwh2EMQRn3jvelFEAoIEeNH4AxxGoeExq_Hhx-jDjj3_g1CCgWlp6CDBBMkxvQM9BNVq7ypnQkW62WlUlcsgzIL7lwZTl3uA90EI1uXhftWtSuLC3CSqdzby_3tgsXjwzwZhuPp4Cm5HYcG84iHjBlhsMIq49rYKNOU6RQLwmkEdQS5MYwzAlNsbYqzlKFMpJHREMWcYM0I7oKb1ruuyo-N9bVcOW9snqvClhsvGcY8hhijLdlrSVOV3lc2k-vKrVTVSATlrpHcNZKHRtvB9V690Sub_uL7KFtAtMCny23zj04ms1nyVx62W-dr-3XYqupdUoYZkS-TgXyek0k8Gt5Lgn8Att-BfQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733840331</pqid></control><display><type>article</type><title>Catalytic Upgrading of Bio-Oils by Ketonization</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Gärtner, Christian A. ; Serrano-Ruiz, Juan Carlos ; Braden, Drew J. ; Dumesic, James A.</creator><creatorcontrib>Gärtner, Christian A. ; Serrano-Ruiz, Juan Carlos ; Braden, Drew J. ; Dumesic, James A.</creatorcontrib><description>Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio‐oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketonization of acids followed by ketonization of esters at higher conversions.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.200900178</identifier><identifier>PMID: 19795436</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Acids - chemistry ; alcohols ; Alcohols - chemistry ; biomass ; Catalysis ; esters ; Esters - chemistry ; ketones ; Ketones - chemistry ; Oils - chemistry</subject><ispartof>ChemSusChem, 2009-01, Vol.2 (12), p.1121-1124</ispartof><rights>Copyright © 2009 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753</citedby><cites>FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19795436$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gärtner, Christian A.</creatorcontrib><creatorcontrib>Serrano-Ruiz, Juan Carlos</creatorcontrib><creatorcontrib>Braden, Drew J.</creatorcontrib><creatorcontrib>Dumesic, James A.</creatorcontrib><title>Catalytic Upgrading of Bio-Oils by Ketonization</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio‐oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketonization of acids followed by ketonization of esters at higher conversions.</description><subject>Acids - chemistry</subject><subject>alcohols</subject><subject>Alcohols - chemistry</subject><subject>biomass</subject><subject>Catalysis</subject><subject>esters</subject><subject>Esters - chemistry</subject><subject>ketones</subject><subject>Ketones - chemistry</subject><subject>Oils - chemistry</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkM1PwjAYhxujEUWvHs1ungbtun4ddSoYCCQC0VvTdh2pjg3XEZ1_vZAR9ObpfQ_P7zk8AFwh2EMQRn3jvelFEAoIEeNH4AxxGoeExq_Hhx-jDjj3_g1CCgWlp6CDBBMkxvQM9BNVq7ypnQkW62WlUlcsgzIL7lwZTl3uA90EI1uXhftWtSuLC3CSqdzby_3tgsXjwzwZhuPp4Cm5HYcG84iHjBlhsMIq49rYKNOU6RQLwmkEdQS5MYwzAlNsbYqzlKFMpJHREMWcYM0I7oKb1ruuyo-N9bVcOW9snqvClhsvGcY8hhijLdlrSVOV3lc2k-vKrVTVSATlrpHcNZKHRtvB9V690Sub_uL7KFtAtMCny23zj04ms1nyVx62W-dr-3XYqupdUoYZkS-TgXyek0k8Gt5Lgn8Att-BfQ</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Gärtner, Christian A.</creator><creator>Serrano-Ruiz, Juan Carlos</creator><creator>Braden, Drew J.</creator><creator>Dumesic, James A.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090101</creationdate><title>Catalytic Upgrading of Bio-Oils by Ketonization</title><author>Gärtner, Christian A. ; Serrano-Ruiz, Juan Carlos ; Braden, Drew J. ; Dumesic, James A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Acids - chemistry</topic><topic>alcohols</topic><topic>Alcohols - chemistry</topic><topic>biomass</topic><topic>Catalysis</topic><topic>esters</topic><topic>Esters - chemistry</topic><topic>ketones</topic><topic>Ketones - chemistry</topic><topic>Oils - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gärtner, Christian A.</creatorcontrib><creatorcontrib>Serrano-Ruiz, Juan Carlos</creatorcontrib><creatorcontrib>Braden, Drew J.</creatorcontrib><creatorcontrib>Dumesic, James A.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gärtner, Christian A.</au><au>Serrano-Ruiz, Juan Carlos</au><au>Braden, Drew J.</au><au>Dumesic, James A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Upgrading of Bio-Oils by Ketonization</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2009-01-01</date><risdate>2009</risdate><volume>2</volume><issue>12</issue><spage>1121</spage><epage>1124</epage><pages>1121-1124</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio‐oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketonization of acids followed by ketonization of esters at higher conversions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>19795436</pmid><doi>10.1002/cssc.200900178</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1864-5631
ispartof ChemSusChem, 2009-01, Vol.2 (12), p.1121-1124
issn 1864-5631
1864-564X
language eng
recordid cdi_proquest_miscellaneous_733840331
source Wiley-Blackwell Read & Publish Collection
subjects Acids - chemistry
alcohols
Alcohols - chemistry
biomass
Catalysis
esters
Esters - chemistry
ketones
Ketones - chemistry
Oils - chemistry
title Catalytic Upgrading of Bio-Oils by Ketonization
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T16%3A18%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Catalytic%20Upgrading%20of%20Bio-Oils%20by%20Ketonization&rft.jtitle=ChemSusChem&rft.au=G%C3%A4rtner,%20Christian%E2%80%85A.&rft.date=2009-01-01&rft.volume=2&rft.issue=12&rft.spage=1121&rft.epage=1124&rft.pages=1121-1124&rft.issn=1864-5631&rft.eissn=1864-564X&rft_id=info:doi/10.1002/cssc.200900178&rft_dat=%3Cproquest_cross%3E733840331%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3828-77c9c3a3af8bce2fb67bd3958620b208cc78750d3eed3fd71f9d2cb014853b753%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=733840331&rft_id=info:pmid/19795436&rfr_iscdi=true