Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes

Three-dimensional carbon nanotube scaffolds created using micromachined Si/SiO2 templates are used as nanoparticulate filters and support membranes for gas-phase heterogeneous catalysis. The filtering efficiency of better than 99% is shown for the scaffolds in filtering submicrometer particles from...

Full description

Saved in:
Bibliographic Details
Published in:ACS nano 2010-04, Vol.4 (4), p.2003-2008
Main Authors: Halonen, Niina, Rautio, Aatto, Leino, Anne-Riikka, Kyllönen, Teemu, Tóth, Géza, Lappalainen, Jyrki, Kordás, Krisztián, Huuhtanen, Mika, Keiski, Riitta L, Sápi, András, Szabó, Mária, Kukovecz, Ákos, Kónya, Zoltán, Kiricsi, Imre, Ajayan, Pulickel M, Vajtai, Robert
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243
cites cdi_FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243
container_end_page 2008
container_issue 4
container_start_page 2003
container_title ACS nano
container_volume 4
creator Halonen, Niina
Rautio, Aatto
Leino, Anne-Riikka
Kyllönen, Teemu
Tóth, Géza
Lappalainen, Jyrki
Kordás, Krisztián
Huuhtanen, Mika
Keiski, Riitta L
Sápi, András
Szabó, Mária
Kukovecz, Ákos
Kónya, Zoltán
Kiricsi, Imre
Ajayan, Pulickel M
Vajtai, Robert
description Three-dimensional carbon nanotube scaffolds created using micromachined Si/SiO2 templates are used as nanoparticulate filters and support membranes for gas-phase heterogeneous catalysis. The filtering efficiency of better than 99% is shown for the scaffolds in filtering submicrometer particles from air. In the hydrogenation of propene to propane reaction low activation energy of E a ∼27.8 ± 0.6 kJ·mol−1, a considerably high turnover rate of ∼1.1 molecules·Pd site−1·s−1 and durable activity for the reaction are observed with Pd decorated membranes. It is demonstrated that appropriate engineering of macroscopic-ordered nanotube architectures can lead to multifunctional applications.
doi_str_mv 10.1021/nn100150x
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_733914288</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>733914288</sourcerecordid><originalsourceid>FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243</originalsourceid><addsrcrecordid>eNptkE1Lw0AQhhdRbP04-AckFxEP0f1KsjlKtSrUD2gFb2GymWDKJlt3N2D_vZHWnjzNMDzvy_AQcsboNaOc3XQdo5Ql9HuPjFku0piq9GN_tydsRI68X1KaZCpLD8mIU5HmSqkxgcWnQ4zvmhY739gOTDQBV9oueoHOhr7EaK6hrq2pfAQ-egMXGt0bCBhNGxPQDeeuGkIBzNqHaN6vVtaF6Bnb0kGH_oQc1GA8nm7nMXmf3i8mj_Hs9eFpcjuLQTAZ4jxNoSqBy4zLMqc6SUBKnWdMYZbQWmohecVqyXSSVZWSgGlSi5wj1pBpLsUxudz0rpz96tGHom28RmOGJ2zvi0yInEmu1EBebUjtrPcO62LlmhbcumC0-BVa7IQO7Pm2tS9brHbkn8EBuNgAoH2xtL0bFPp_in4ARNV9eQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733914288</pqid></control><display><type>article</type><title>Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes</title><source>Access via American Chemical Society</source><creator>Halonen, Niina ; Rautio, Aatto ; Leino, Anne-Riikka ; Kyllönen, Teemu ; Tóth, Géza ; Lappalainen, Jyrki ; Kordás, Krisztián ; Huuhtanen, Mika ; Keiski, Riitta L ; Sápi, András ; Szabó, Mária ; Kukovecz, Ákos ; Kónya, Zoltán ; Kiricsi, Imre ; Ajayan, Pulickel M ; Vajtai, Robert</creator><creatorcontrib>Halonen, Niina ; Rautio, Aatto ; Leino, Anne-Riikka ; Kyllönen, Teemu ; Tóth, Géza ; Lappalainen, Jyrki ; Kordás, Krisztián ; Huuhtanen, Mika ; Keiski, Riitta L ; Sápi, András ; Szabó, Mária ; Kukovecz, Ákos ; Kónya, Zoltán ; Kiricsi, Imre ; Ajayan, Pulickel M ; Vajtai, Robert</creatorcontrib><description>Three-dimensional carbon nanotube scaffolds created using micromachined Si/SiO2 templates are used as nanoparticulate filters and support membranes for gas-phase heterogeneous catalysis. The filtering efficiency of better than 99% is shown for the scaffolds in filtering submicrometer particles from air. In the hydrogenation of propene to propane reaction low activation energy of E a ∼27.8 ± 0.6 kJ·mol−1, a considerably high turnover rate of ∼1.1 molecules·Pd site−1·s−1 and durable activity for the reaction are observed with Pd decorated membranes. It is demonstrated that appropriate engineering of macroscopic-ordered nanotube architectures can lead to multifunctional applications.</description><identifier>ISSN: 1936-0851</identifier><identifier>EISSN: 1936-086X</identifier><identifier>DOI: 10.1021/nn100150x</identifier><identifier>PMID: 20369888</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS nano, 2010-04, Vol.4 (4), p.2003-2008</ispartof><rights>Copyright © 2010 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243</citedby><cites>FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20369888$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Halonen, Niina</creatorcontrib><creatorcontrib>Rautio, Aatto</creatorcontrib><creatorcontrib>Leino, Anne-Riikka</creatorcontrib><creatorcontrib>Kyllönen, Teemu</creatorcontrib><creatorcontrib>Tóth, Géza</creatorcontrib><creatorcontrib>Lappalainen, Jyrki</creatorcontrib><creatorcontrib>Kordás, Krisztián</creatorcontrib><creatorcontrib>Huuhtanen, Mika</creatorcontrib><creatorcontrib>Keiski, Riitta L</creatorcontrib><creatorcontrib>Sápi, András</creatorcontrib><creatorcontrib>Szabó, Mária</creatorcontrib><creatorcontrib>Kukovecz, Ákos</creatorcontrib><creatorcontrib>Kónya, Zoltán</creatorcontrib><creatorcontrib>Kiricsi, Imre</creatorcontrib><creatorcontrib>Ajayan, Pulickel M</creatorcontrib><creatorcontrib>Vajtai, Robert</creatorcontrib><title>Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes</title><title>ACS nano</title><addtitle>ACS Nano</addtitle><description>Three-dimensional carbon nanotube scaffolds created using micromachined Si/SiO2 templates are used as nanoparticulate filters and support membranes for gas-phase heterogeneous catalysis. The filtering efficiency of better than 99% is shown for the scaffolds in filtering submicrometer particles from air. In the hydrogenation of propene to propane reaction low activation energy of E a ∼27.8 ± 0.6 kJ·mol−1, a considerably high turnover rate of ∼1.1 molecules·Pd site−1·s−1 and durable activity for the reaction are observed with Pd decorated membranes. It is demonstrated that appropriate engineering of macroscopic-ordered nanotube architectures can lead to multifunctional applications.</description><issn>1936-0851</issn><issn>1936-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkE1Lw0AQhhdRbP04-AckFxEP0f1KsjlKtSrUD2gFb2GymWDKJlt3N2D_vZHWnjzNMDzvy_AQcsboNaOc3XQdo5Ql9HuPjFku0piq9GN_tydsRI68X1KaZCpLD8mIU5HmSqkxgcWnQ4zvmhY739gOTDQBV9oueoHOhr7EaK6hrq2pfAQ-egMXGt0bCBhNGxPQDeeuGkIBzNqHaN6vVtaF6Bnb0kGH_oQc1GA8nm7nMXmf3i8mj_Hs9eFpcjuLQTAZ4jxNoSqBy4zLMqc6SUBKnWdMYZbQWmohecVqyXSSVZWSgGlSi5wj1pBpLsUxudz0rpz96tGHom28RmOGJ2zvi0yInEmu1EBebUjtrPcO62LlmhbcumC0-BVa7IQO7Pm2tS9brHbkn8EBuNgAoH2xtL0bFPp_in4ARNV9eQ</recordid><startdate>20100427</startdate><enddate>20100427</enddate><creator>Halonen, Niina</creator><creator>Rautio, Aatto</creator><creator>Leino, Anne-Riikka</creator><creator>Kyllönen, Teemu</creator><creator>Tóth, Géza</creator><creator>Lappalainen, Jyrki</creator><creator>Kordás, Krisztián</creator><creator>Huuhtanen, Mika</creator><creator>Keiski, Riitta L</creator><creator>Sápi, András</creator><creator>Szabó, Mária</creator><creator>Kukovecz, Ákos</creator><creator>Kónya, Zoltán</creator><creator>Kiricsi, Imre</creator><creator>Ajayan, Pulickel M</creator><creator>Vajtai, Robert</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100427</creationdate><title>Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes</title><author>Halonen, Niina ; Rautio, Aatto ; Leino, Anne-Riikka ; Kyllönen, Teemu ; Tóth, Géza ; Lappalainen, Jyrki ; Kordás, Krisztián ; Huuhtanen, Mika ; Keiski, Riitta L ; Sápi, András ; Szabó, Mária ; Kukovecz, Ákos ; Kónya, Zoltán ; Kiricsi, Imre ; Ajayan, Pulickel M ; Vajtai, Robert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Halonen, Niina</creatorcontrib><creatorcontrib>Rautio, Aatto</creatorcontrib><creatorcontrib>Leino, Anne-Riikka</creatorcontrib><creatorcontrib>Kyllönen, Teemu</creatorcontrib><creatorcontrib>Tóth, Géza</creatorcontrib><creatorcontrib>Lappalainen, Jyrki</creatorcontrib><creatorcontrib>Kordás, Krisztián</creatorcontrib><creatorcontrib>Huuhtanen, Mika</creatorcontrib><creatorcontrib>Keiski, Riitta L</creatorcontrib><creatorcontrib>Sápi, András</creatorcontrib><creatorcontrib>Szabó, Mária</creatorcontrib><creatorcontrib>Kukovecz, Ákos</creatorcontrib><creatorcontrib>Kónya, Zoltán</creatorcontrib><creatorcontrib>Kiricsi, Imre</creatorcontrib><creatorcontrib>Ajayan, Pulickel M</creatorcontrib><creatorcontrib>Vajtai, Robert</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS nano</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Halonen, Niina</au><au>Rautio, Aatto</au><au>Leino, Anne-Riikka</au><au>Kyllönen, Teemu</au><au>Tóth, Géza</au><au>Lappalainen, Jyrki</au><au>Kordás, Krisztián</au><au>Huuhtanen, Mika</au><au>Keiski, Riitta L</au><au>Sápi, András</au><au>Szabó, Mária</au><au>Kukovecz, Ákos</au><au>Kónya, Zoltán</au><au>Kiricsi, Imre</au><au>Ajayan, Pulickel M</au><au>Vajtai, Robert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes</atitle><jtitle>ACS nano</jtitle><addtitle>ACS Nano</addtitle><date>2010-04-27</date><risdate>2010</risdate><volume>4</volume><issue>4</issue><spage>2003</spage><epage>2008</epage><pages>2003-2008</pages><issn>1936-0851</issn><eissn>1936-086X</eissn><abstract>Three-dimensional carbon nanotube scaffolds created using micromachined Si/SiO2 templates are used as nanoparticulate filters and support membranes for gas-phase heterogeneous catalysis. The filtering efficiency of better than 99% is shown for the scaffolds in filtering submicrometer particles from air. In the hydrogenation of propene to propane reaction low activation energy of E a ∼27.8 ± 0.6 kJ·mol−1, a considerably high turnover rate of ∼1.1 molecules·Pd site−1·s−1 and durable activity for the reaction are observed with Pd decorated membranes. It is demonstrated that appropriate engineering of macroscopic-ordered nanotube architectures can lead to multifunctional applications.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>20369888</pmid><doi>10.1021/nn100150x</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1936-0851
ispartof ACS nano, 2010-04, Vol.4 (4), p.2003-2008
issn 1936-0851
1936-086X
language eng
recordid cdi_proquest_miscellaneous_733914288
source Access via American Chemical Society
title Three-Dimensional Carbon Nanotube Scaffolds as Particulate Filters and Catalyst Support Membranes
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T02%3A41%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Three-Dimensional%20Carbon%20Nanotube%20Scaffolds%20as%20Particulate%20Filters%20and%20Catalyst%20Support%20Membranes&rft.jtitle=ACS%20nano&rft.au=Halonen,%20Niina&rft.date=2010-04-27&rft.volume=4&rft.issue=4&rft.spage=2003&rft.epage=2008&rft.pages=2003-2008&rft.issn=1936-0851&rft.eissn=1936-086X&rft_id=info:doi/10.1021/nn100150x&rft_dat=%3Cproquest_cross%3E733914288%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a314t-966adba24724b90c55a44c9718e750f4c342d1f41c57dd84ae65f392eefa7c243%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=733914288&rft_id=info:pmid/20369888&rfr_iscdi=true