Simple Lithium(I) Salt with a Microporous Structure and Its Gas Sorption Properties

Thoroughly absorbing: The simple combination of lithium ions and isonicotinate anions (1) leads to the formation of a lightweight salt (see picture; C black, O red, N blue, Li purple) that is able to reversibly sorb H2 , N2 , CO2 , and CH4 . The salt exists as a 3D network of microchannels that are...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-02, Vol.49 (6), p.1087-1089
Main Authors: Abrahams, Brendan F, Grannas, Martin J, Hudson, Timothy A, Robson, Richard
Format: Article
Language:English
Subjects:
coordination polymers
gas sorption
hydrogen
lithium
microporous materials
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Summary:Thoroughly absorbing: The simple combination of lithium ions and isonicotinate anions (1) leads to the formation of a lightweight salt (see picture; C black, O red, N blue, Li purple) that is able to reversibly sorb H2 , N2 , CO2 , and CH4 . The salt exists as a 3D network of microchannels that are occupied by solvent molecules.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200906322